As described in Exercise 14.41, the decomposition of sulfurylchloride (SO2Cl2) is a first-order process. The rateconstant for the decomposition at 660 K is 4.5 x 10-2 s-1.(a) If we begin with an initial SO2Cl2 pressure of 450 torr,what is the partial pressure of this substance after 60 s?(b) At what time will the partial pressure of SO2Cl2 declineto one-tenth its initial value?

Chemistry: Principles and Practice
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter13: Chemical Kinetics
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As described in Exercise 14.41, the decomposition of sulfuryl
chloride (SO2Cl2) is a first-order process. The rate
constant for the decomposition at 660 K is 4.5 x 10-2 s-1.
(a) If we begin with an initial SO2Cl2 pressure of 450 torr,
what is the partial pressure of this substance after 60 s?
(b) At what time will the partial pressure of SO2Cl2 decline
to one-tenth its initial value?

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