S2O82−(aq)+3I−(aq)→2SO42−(aq)+I3−(aq) In aqueous solution, the reaction represented by the balanced equation shown above has the experimentally determined rate law: rate=k[S2O82−][I−]. If the concentration of [S2O82−] is doubled while keeping [I−] constant, which of the following experimental results is predicted based on the rate law, and why?

Chemistry: The Molecular Science
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Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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S2O82−(aq)+3I−(aq)→2SO42−(aq)+I3−(aq)

In aqueous solution, the reaction represented by the balanced equation shown above has the experimentally determined rate law: rate=k[S2O82−][I−].

If the concentration of [S2O82−] is doubled while keeping [I−] constant, which of the following experimental results is predicted based on the rate law, and why?

 
 

A The rate of reaction will remain the same, because k will decrease by half.

 

B The rate of reaction will double, because the rate is directly proportional to [S2O82−]..

 

C The rate of reaction will increase by a factor of four, because two moles of SO42− are produced for each mole of S2O82− consumed.

 
 

D The rate of reaction will increase by a factor of four, because the reaction is second order overall.

 

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