At elevated temperatures, nitrogen dioxide decomposes to nitric acid and molecular oxygen: Concentration-time data for consumption of NO, at 300°C are as follows: NO,(g) → NO(g) + ½ O2lg) Time (s) Time (s) [NO2] 8.00 x 103 [NO;] 4.29 x 10-3 3.48 x 10-3 2.93 x 10-3 2.53 x 10-3 200 50 6.58 × 10-3 300 5.59 x 10-3 4.85 × 10-3 100 400 150 500 a. What is the order of the reaction? b. What is the value of the rate constant? c. What is the concentration of NO, at t=20.0min?

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.36PAE: The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...
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Example 5.2
At elevated temperatures, nitrogen dioxide decomposes to nitric acid and
molecular oxygen:
NO,(g) → NO(g) + ½ O,(g)
Concentration-time data for consumption of NO, at 300°C are as follows:
Time (s)
Time (s)
[NO:]
8.00 x 10-3
[NO2]
4.29 x 10-3
3.48 × 10-3
2.93 x 10-3
2.53 x 10-3
200
6.58 x 10-3
5.59 x 10-3
4.85 x 10-3
50
300
100
400
150
500
a. What is the order of the reaction?
b. What is the value of the rate constant?
c. What is the concentration of NO, at t=20.0min?
Transcribed Image Text:Example 5.2 At elevated temperatures, nitrogen dioxide decomposes to nitric acid and molecular oxygen: NO,(g) → NO(g) + ½ O,(g) Concentration-time data for consumption of NO, at 300°C are as follows: Time (s) Time (s) [NO:] 8.00 x 10-3 [NO2] 4.29 x 10-3 3.48 × 10-3 2.93 x 10-3 2.53 x 10-3 200 6.58 x 10-3 5.59 x 10-3 4.85 x 10-3 50 300 100 400 150 500 a. What is the order of the reaction? b. What is the value of the rate constant? c. What is the concentration of NO, at t=20.0min?
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