For the following reaction 5 experiments have been run and the data collected is in the following table: 4 HBr(g) + O2(g)--->2 Br2(g) + 2 H2O(g) Experiment [HBr], M [O2 ], M Rate, M/s (aka mol/L.s) 1 0.120 0.490 0.0267 2 0.142 0.120 0.00190 3 0.120 0.630 0.0442 4 0.230 0.630 0.0846 5 0.630 0.863 0.435 a) Find the order of the reaction with respect to HBr. b)Find the order of the reaction with respect to O2.[Hint, need to do long version (not the shortcut) to find rate order here] c)What is the overall order of the reaction?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter14: Chemical Equilibrium
Section: Chapter Questions
Problem 97CP
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For the following reaction 5 experiments have been run and the data collected is in the following table:

4 HBr(g) + O2(g)--->2 Br2(g) + 2 H2O(g)

Experiment [HBr], M [O], M Rate, M/s (aka mol/L.s)
1 0.120 0.490 0.0267
2 0.142 0.120 0.00190
3 0.120 0.630 0.0442
4 0.230 0.630 0.0846
5 0.630 0.863 0.435

a) Find the order of the reaction with respect to HBr.

b)Find the order of the reaction with respect to O2.[Hint, need to do long version (not the shortcut) to find rate order here]

c)What is the overall order of the reaction?

d)Write the rate expression.

e) Calculate the rate constant, k

f) If the concentration of HBr and O2 are 1.5 x 10-3 M and 3.25 x 10-3 respectively, what is the rate of the reaction?

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