B AG = 18.3 kJ/mol AG = 5.9 kJ/m. %3D ion

Chemistry by OpenStax (2015-05-04)
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ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter5: Thermochemistry
Section: Chapter Questions
Problem 40E: Using the data in the check your learning section of Example 5.5, calculate H in kJ/mol of AgNO3(aq)...
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The energy difference between a tert-butyl group going from equatorial to axial in a cyclohexane is 18.3 kJ/mol. When two of the carbon atoms are replaced with oxygen atoms (molecule B) the energy difference between the two chair conformations drops to 5.9 kJ/mol. Explain this difference. (Hint: Consider what makes putting groups axial unfavorable).

B
AG = 18.3 kJ/mol
AG = 5.9 kJ/m.
%3D
ion
Transcribed Image Text:B AG = 18.3 kJ/mol AG = 5.9 kJ/m. %3D ion
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