(b) Draw the Frontier orbital diagram to show the possible electronic transitions of a,B-unsaturated carbonyl compounds.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
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( do 7 b
7. (a) The identity sticker of the container of
the following three compounds got
removed :
NO2
NH2
CH3
NH2
H3C,
ÑO2
NO2
(C)
(A)
The UV-spectra of the compounds
shows absorption at A max 252 nm,
375 nm and 385 nm (not is order).
Match the structure with appropriate
UV-spectra with explanation.
(B)
Draw the Frontier orbital diagram to
(b)
show the possible electronic transitions of
a,B-unsaturated carbonyl compounds.
Write the mathematical expression for
(c)
metastable ion, indicating the terms
involved. Explain the significance of
metastable ion considering the MS of
anisidine at m/z 123, 108, 80, 94-8 and
59.2
Transcribed Image Text:7. (a) The identity sticker of the container of the following three compounds got removed : NO2 NH2 CH3 NH2 H3C, ÑO2 NO2 (C) (A) The UV-spectra of the compounds shows absorption at A max 252 nm, 375 nm and 385 nm (not is order). Match the structure with appropriate UV-spectra with explanation. (B) Draw the Frontier orbital diagram to (b) show the possible electronic transitions of a,B-unsaturated carbonyl compounds. Write the mathematical expression for (c) metastable ion, indicating the terms involved. Explain the significance of metastable ion considering the MS of anisidine at m/z 123, 108, 80, 94-8 and 59.2
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