(b) Give the full name, the oxidation state and the valence shell electronic configuration forthe metal in each of the following compounds.(1) Na[Fe(CO).](i) [Co(OH)]Ck(iii) W(CO),(c) Give one example in each case of a tetrahedral transition metal coordination compoundthat exhibits (i) coordination isomerism and (ii) geometric isomerism. Draw structures ofall the isomers in each case.Answer either (d) or (e)(d) Consider the compound [Fe(CN);(NH:)4]" and answer the following questions:(i) Which is the oxidation state of the metal and how many d electrons does it have?(ii) Draw the crystal field splitting pattern of the compound. This should include adiagram that shows the relative energy levels and how many electrons are found in cach dorbital, as well as orbital and symmetry labels.

Note: As per our guidelines, we are supposed to answer only the sub-parts of the first question…

Answered: (b) Give the full name, the oxidation…

(b) Give the full name, the oxidation state and the valence shell electronic configuration for the metal in each of the following compounds. (i) Na»[Fe(CO),] (ii) [Co(OH2)6]Ch (iii) W(CO),

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 63AP

See similar textbooks

Related questions

Q: The complex [Co(NH3)6]Cl3 is yellow orange while [Co(OH2)3F3] is blue. Suggest an explanation for…

A: The colour shown by the complexes are the complementary colours of the wavelength of light absorbed.…

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: Ionization isomers in coordination complexes are identified by the ligands present outside the…

Q: Iron(III) forms octahedral complexes. Sketch the structures of all the distinct isomers of…

A: [Fe(en)2Cl2]+ has cis and trans both type of isomers. Where , "en" stands for ethylene di-amine…

Q: In octahedral complexes, for which d electron counts is it possible to have high-spin and low-spin…

A: The coordination complexes can be defined as the complex compounds which have coordinate linkage…

Q: Describe and differentiate strong field ligands and weak field ligands. Give two examples for each.

A: Given; We have to differentiate between weak field ligands and strong field ligands with two…

Q: Explain the differences between weak-field and strong-field metal complexes?

A: Differences between weak-field and strong-field metal complexes:

Q: Illustrate the concepts of Transition-Metal Complexes?

A: Transition metal complexes are also named as coordination compounds. These complexes involve ions of…

Q: Two Fe (II) complexes are both low spin but have different ligands. A solution of the other is red.…

A: The stronger the field, the greater the separation (in energy) between the split levels. Electrons…

Q: Which ordering correctly describes the tendency of a ligand to direct ligand substitution in a…

A: Trans effect can be defined as the effect of a ligand towards substitution on other ligands which is…

Q: Ligand A, B, and C form complexes with a metal cation resulting to violet, indigo, and blue aqueous…

Q: How many different formulas are there for octahedral complexes with a metal M and four ligands A, B,…

A: The complexes in which the central metal atom is surrounded by six ligands are called an octahedral…

Q: Carbon monoxide, CO, is an important ligand in coordinationchemistry. When CO is reacted with nickel…

A: Nickel tetracarbonyl is a tetrahedral compound since there are 4 ligands attached to the compound by…

Q: By plotting the structure of the dinitro tetraammin cobalt (III) chloride complex compound, specify…

A: Any compound that is written within square brackets is called a coordination compound. The ions…

Q: give an example of hexadentate ligand.

A: Ligands with six atoms with six lone pair of electrons that coordinates with metal atom are called…

Q: The complexes [V(H2O)6]3+ and [VF6]3- are both known. What gives rise to the colors of these…

A: The striking colors exhibited by the complexes are caused due to excitation of an electron from…

Q: For the ethylenediaminetetraacetatochromat(III) complex ion, in which order is the coordination…

A: The complex given is ethylenediaminetetraacetate Chromate(III).

Q: A metal ion uses d2sp3 orbitals when forming a complex. What is its coordination number and the…

A: The given data : The hybridization of the metal ion = d2sp3 To determine = The coordination number…

Q: How can know the cis and trans of geometrical isomerism in octahedral complexes?

A: Compounds have the same chemical formula but the different stereochemical structure is called…

Q: Explain the differences between high-spin and low-spin metal complexes.

A: Complexes with weak field ligands have the same number of unpaired electrons as the free metal ion…

Q: Draw the structure of the complex, [Ni(NH3)6][BF4]2, including approximate bond angles (in °).…

A: The objective of the question is to draw the given complex and write the angle and geometry.

Q: Mention and draw the types of structural isomerism present in metal complexes and indicate to…

A: Answers are explained below.

Q: The lobes of which d orbitals point directly betweenthe ligands in (a) octahedral geometry, (b)…

A: In Octahedral the ligands are pointing towards the X, Y & Z axis. The 5 d orbitals are: dxy…

Q: Consider the octahedral complexes of Co3+. Complete the following statements. The strong field…

A: The answer is given as follows

Q: When we consider the reaction of Fe3+ ion (SCN) with its ligand, by showing the ion-ligand bond in…

A: The reaction between Fe3+ and SCN- could be given as, Fe3+aq+SCN-aq→FeSCN2+ SCN- is a thiocyanate…

Q: What is the relationship between observed colour of the complex and the wavelength of light absorbed…

A: When light falls on a complex, certain part will get absorbed. If the crystal field splitting energy…

Q: The complex [COF6]¯ absorbs light at a wavelength of 290 nm. What is the value of the crystal filed…

Q: 2. Red crystalline [NiCl,(PPh,CH,Ph)2] is diamagnetic. On heating to 387 K for 2 hours, a blue-…

A: In this complex, nickel is in +2 oxidation state and it has valence shell electronic configuration…

Q: Explain the terms diamagnetic and paramagnetic NiCl2(PPh3)2 is a green paramagnetic solid, while cis…

A: If a compound have unpaired electrons in its orbital, then the compound is known as paramagnetic in…

Q: Compare the ligand field strengths of CO and Cl, in terms of the types of bonds in which they can be…

A: CO is Sigma donor and pi acceptor ligand while Cl is only Sigma donor ligand .thus there type of…

Q: Give 5 examples of metal coordination complexes and enumerate their importance

A: A question based on coordination complexes that is to be accomplished.

Q: How is Ao defined for octahedral transition metal complexes?

Q: Which of the following is a tetradentate ligand?

A: Tetradentate ligand is defined as a ligand that has an ability to bind to four donor atoms to a…

Q: Let us consider the following coordination complexes: [Fe(CN6)]3- Given that the chloride ion and…

A: The given coordination complex is a cyanide containing complex, and cyanide is a strong field…

Q: There

A: We will identify same molecule and isomer of 1 molecule

Q: Indicate the likely coordination number of the metal in each of the following complexes: (a)…

A: Coordination number is the sum of ligand atoms attached to the central atom. That means the ligands…

Q: A coordination compound has been determined to be composed of 18.4% Co, 26.6% NH3, 30.0% SO4 , and…

A: A co-ordination compound is a compound containing a central metal atom bound to ligands. The central…

Q: The number of unpaired electrons in dº, low spin, octahedral complex is-

A: Chemical compounds that consist of an arrangement of neutral molecules or anions that are bound to a…

Q: Giving one example in each of the following cases, discuss briefly the role of coordination…

A: Introduction- Coordination compounds- These are the compounds which contain a complex part formed…

Q: 1. Briefly explain the meaning of the following terms: ligand, complex, monodentate ligand,…

Q: Which atom is a common linkage site in polydentate ligands?

A: Polydendate ligands are those ligands which have more than 2 donar atoms .

Q: What is the oxidation state of the metal centre in the [Cr(CO3)3(C6H6)] complex?

A: Explanation- Cr(CO3)3(C6H6)] complex is the name (η 6 -benzene ) tricarbonyl chromium(0).…

Q: Suppose that you want to determine whether a ligand X is a weak-field or strong-field ligand. Would…

A: Strong field ligand are able to pair the electrons while weak field ligand are not able to pair…

Q: A coordination compound has the following composition (by mass %): 23.53% Co; 42.47% Cl, and 34.00%…

Q: Describe the makeup of a complex ion, including the natureof the ligands and their interaction with…

A: Complex molecules are a section of inorganic chemistry . A complex is formed when a metal center is…

Q: Give the systematic name of this coordination compound. [(en), ]Cl, systematic name:

A: Rules for naming complex compounds :- In coordination sphere ligands are named fist in alphabetical…

Q: Write the Werner's formula of a coordination compound called Sodium diaquatetrachlorocobaltate(Il).

A: Werner's theory tells us that metal have two valencies. They are primary and secondary valency. The…

Q: For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify(i) the oxidation number of…

A: Organometallic compounds contains a bond between a metal and a carbon atom of an organic ligand.…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

(b) Give the full name, the oxidation state and the valence shell electronic configuration for
the metal in each of the following compounds.
(1) Na[Fe(CO).]
(i) [Co(OH)]Ck
(iii) W(CO),
(c) Give one example in each case of a tetrahedral transition metal coordination compound
that exhibits (i) coordination isomerism and (ii) geometric isomerism. Draw structures of
all the isomers in each case.
Answer either (d) or (e)
(d) Consider the compound [Fe(CN);(NH:)4]" and answer the following questions:
(i) Which is the oxidation state of the metal and how many d electrons does it have?
(ii) Draw the crystal field splitting pattern of the compound. This should include a
diagram that shows the relative energy levels and how many electrons are found in cach d
orbital, as well as orbital and symmetry labels.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step by step

Solved in 4 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?
What is the coordination number of the central metal atom in the following complexes? (a) [Fe(H2O)63+] (b) [Pt(NH3)Br3] (c) [V(en)Cl42] (d) [Au(CN)2+]
Describe the makeup of a complex ion, including the natureof the ligands and their interaction with the central metal ion.Explain how a complex ion can be positive or negative and howit occurs as part of a neutral coordination compound.
Give 5 examples of metal coordination complexes and enumerate their importance
A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the structure of such complex.
Explain in words how potassium aluminum sulfate is formed via ligand exchange. Indicate clearly the ligands inolved
Isn't An electron-rich transition metal has a low oxidation state, meaning that the metal centre has gained electrons from the nitrogen on NO when it coordinates as a ligand? Therefore, N-O bond length decases.
Complete the structure for the mer-triaquatrichloridocobalt(III) coordination complex and Identify the overall charge of the complex.
Both H2O and ethylenediamine (en) have two nonbonding pairs of electrons. Whycan en act as a bidentate ligand whereas water cannot?
Draw one facial and one meridional (fac- and mer-) isomer of the coordination complex of the general formula MX3Y3 (where M is the metal center, X and Y are two types of monodentate ligands).
For each of the following metals, write the electronic configurationof the atom and its 3+ ion: (a) Fe, (b) Mo, (c) Co.Draw the crystal-field energy-level diagram for the d orbitalsof an octahedral complex, and show the placement of the delectrons for each 3+ ion, assuming a weak-field complex.How many unpaired electrons are there in each case?
Ligand A, B, and C form complexes with a metal cation resulting to violet, indigo, and blue aqueous solutions, respectively. Arrange the ligands in order of increasing field strength.