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For each of the following reactions, predict the product by drawing a reasonable mechanism. What controls the regiochemistry in each case???
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- Please provide a justification for the following statement: lithium chloride dissolves in polarorganic solvents. What would you expect for other group I metal halides?For the powder with composition 9wt.% Al, 3wt.% Ni and 88wt.% Mg Calculate the possible Gibb's Free energy (which reactions are most favorable) in a closed system of 610 °CThe Ksp at 298 K for iron(II) fluoride is 2.4 * 10-6. (a) Write a half-reaction that gives the likely products of the two-electron reduction of FeF21s2 in water.
- Manganese silicide has the empirical formula MnSi andmelts at 1280 °C. It is insoluble in water but does dissolvein aqueous HF. (a) What type of compound do you expectMnSi to be: metallic, molecular, covalent-network, orionic? (b) Write a likely balanced chemical equation for thereaction of MnSi with concentrated aqueous HF.1-Why σ2px lie at higher energy level than π2py and π2pz in N2? 2-Discuss the structure of [Ni (CN)6]-2 on base of VBTStrontium titanate (SrTiO3) is another wide bandgap semiconductor that has been investigated for use in dyesensitized solar cells. Depending on morphology and pHthe conduction band of SrTiO3 lies around -.2 V vs. SHE.What energies for the HOMO and LUMO of a sensitizingdye would you specify for electron injection into the conduction band of strontium titanate and for water oxidationby the radical cation formed by photoexcitation?
- (i) What type of non-stoichiometric point defect is responsible for the pink colour of LiCl?(ii) What type of stoichiometric defect is shown by NaCl?Cite the overall reaction for the extraction of (a) Fe, (b) Al, and (c) Mg from their corresponding metal oxides when coupled with the oxidation of C (s) to CO (g). Which of these metals can be extracted from its oxide at 1800 °C?Consider the reaction between dissolved Fe2+ and elemental sulfur (S0) to form hematite (Fe2O3) and sulfide a) Identify the oxidant and reductant in this reaction, determine half-reactions, and balance thereaction. b) Is this reaction thermodynamically favorable? c) Would you expect HS- to react readily with Fe2O3 (i.e. the reverse of the reaction)?
- Quickly plezz!! The levigating agent role in Suppositories manufacturing ??The stretching vibration of CO (g) is found at 2138 cm-1. The band is almost always displaced to lower wave number upon coordination of CO to a metal. Explain why this is the case.Use data from CRC_Std_Thermodyn_Substances and CRC_Std_Thermodyn_Aqueous-Ions to calculate ΔrH∘ΔrH∘ (in kj/mol) for the following at 25 ∘∘C. 2CaC2O4(s)⟶4CO(g)+O2(g)+2CaO(s)