(b) The esterification reaction above was carried out in the presence of hydrochloric acid as the catalyst. State the effect on the equilibrium position and the rate of attainment of equilibrium if the concentration of the acid catalyst were to be increased. (c) (i) Identify which bonds are broken and which bonds are made in the esterification reaction. Bonds broken: Bonds made: (ii) Explain why AH for this reaction is not exactly zero. (A calculation is not required.)

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter10: Organic Chemistry
Section: Chapter Questions
Problem 10.57P: Aspirin is prepared by the reaction of salicylic- acid with acetic anhydride as shown in the...
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Ethanoic acid and ethanol react together to form the ester ethyl ethanoate,
CH₂COOC₂H, and water.
CH₂COOH (1) + CH₂CH₂OH(I) = CH₂COOCH₂CH₂(1) + H₂O(l)
Transcribed Image Text:Ethanoic acid and ethanol react together to form the ester ethyl ethanoate, CH₂COOC₂H, and water. CH₂COOH (1) + CH₂CH₂OH(I) = CH₂COOCH₂CH₂(1) + H₂O(l)
(b) The esterification reaction above was carried out in the presence of hydrochloric
acid as the catalyst.
State the effect on the equilibrium position and the rate of attainment of
equilibrium if the concentration of the acid catalyst were to be increased.
(c) (i) Identify which bonds are broken and which bonds are made in the
esterification reaction.
Bonds broken:
Bonds made:
(ii) Explain why AH for this reaction is not exactly zero.
(A calculation is not required.)
Transcribed Image Text:(b) The esterification reaction above was carried out in the presence of hydrochloric acid as the catalyst. State the effect on the equilibrium position and the rate of attainment of equilibrium if the concentration of the acid catalyst were to be increased. (c) (i) Identify which bonds are broken and which bonds are made in the esterification reaction. Bonds broken: Bonds made: (ii) Explain why AH for this reaction is not exactly zero. (A calculation is not required.)
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