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be shown as CH: a II CH CH3 CH3 CH3 CHs CH3 CH3 CI CH3 6) Actral (n) Chiral Cộ Chira

be shown as CH: a II CH CH3 CH3 CH3 CHs CH3 CH3 CI CH3 6) Actral (n) Chiral Cộ Chira

Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 6CTQ
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Please use the table Which is the major and minor product for this molecule reacting with cl2
"For each halogen, reactivities with four types of alkane C-H bonds are normalized to the reactivity of th 2-151 O (tert-Butyl bromidej 90% : Less (primary) 0.06%mi 10% Expected (statistical) ratio C-H bond reactivity Experimental ratio More (tertiary) 99.94% In Summary Increased reactivity goes hand in hand with reduced selectivity in radied. stitution reactions. Fluorine and chlorine, the more reactive halogens, discriminate ba the various types of C-H bonds much less than does the less reactive bromine (Table 3. Relative Reactivities of the Four Types of Alkane C-H Bonds in Halogenations Table 3-6 F• e Cl. (25°C, gas) C-H bond Br (150°C, g (25°C, gas) CH3-H RCH-H" R,CH-H R;C-H 0.5 1 0.004 0.002 1.2 1 1 1.4 4 80 primary C-H bond. 1700
Transcribed Image Text:"For each halogen, reactivities with four types of alkane C-H bonds are normalized to the reactivity of th 2-151 O (tert-Butyl bromidej 90% : Less (primary) 0.06%mi 10% Expected (statistical) ratio C-H bond reactivity Experimental ratio More (tertiary) 99.94% In Summary Increased reactivity goes hand in hand with reduced selectivity in radied. stitution reactions. Fluorine and chlorine, the more reactive halogens, discriminate ba the various types of C-H bonds much less than does the less reactive bromine (Table 3. Relative Reactivities of the Four Types of Alkane C-H Bonds in Halogenations Table 3-6 F• e Cl. (25°C, gas) C-H bond Br (150°C, g (25°C, gas) CH3-H RCH-H" R,CH-H R;C-H 0.5 1 0.004 0.002 1.2 1 1 1.4 4 80 primary C-H bond. 1700
be shown as CH1 .CHa CH CH II CH3 H3C HyC. CHs HC- EHD. CH3 CH3 CI 0 Actiral (w) Chiral () Chital Nou tha D ond Saba figuwotio ohiuol 1.
Transcribed Image Text:be shown as CH1 .CHa CH CH II CH3 H3C HyC. CHs HC- EHD. CH3 CH3 CI 0 Actiral (w) Chiral () Chital Nou tha D ond Saba figuwotio ohiuol 1.
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