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- Three of the following amines can be prepared by the Gabriel synthesis; three cannot. Write equations showing the successful applications of this method. (a) Butylamine (b) Isobutylamine (c) tert-Butylamine (d) 2-Phenylethylamine (e) N-Methylbenzylamine (f) AnilineDefine the Mechanism - Conversion of Carboxylic Acids to Amides with DCCPropose a reasonable Phase I and a Phase II metabolite for the following
- Benzenesulfonyl chloride or p-toluenesulfonylchloride give N-substituted sulfonamides with primary and secondary amines. The derivative consisting of primary amines is insoluble in dilute NaOH.RightFalseStarting with benzene synthesize the amino acid phenylalanine 1. using the strecker approach 2. by reductive aminationBenzenesulfonyl chloride or p-toluenesulfonylchloride give N-substituted sulfonamides with primary and secondary amines. The derivative consisting of primary amines is insoluble in dilute NaOH. Is that true or false?
- Give the products expected when the following tertiary amines are treated with a peroxyacid and heated.N,N-diethylhexan-2-amineShow how to synthesize the following amines from the indicated starting materials byreductive amination. (±)-amphetamine 1-phenylpropan-2-oneShow how you would use appropriate acyl chlorides and amines to synthesize thefollowing amides.(a) N,N-dimethylacetamide (b) acetanilide (PhNHCOCH3)(c) cyclohexanecarboxamide (d)
- Comment on the solubilities of the following amines in water. Please write soluble or insoluble next to the compound. 1. Cyclohexylamine - 2. Aniline - 3. Pyridine - 4. Triethylamine -When the (R,R) isomer of the amine shown is treated with an excess of methyl iodide, then silver oxide, then heated, the majorproduct is the Hofmann product.) Some Zaitsev product is also formed. It has the (E) configuration. When the same amine is treated with mCPBA and heated, theZaitsev product has the (Z) configuration. Use stereochemical drawings of the transition states to explain these observationsWhat acyl chloride and amine are required to synthesize the following amides?a. N-ethylbutanamide b. N,N-dimethylbenzamide