Br CH₂ 2 H₂C H H 3 3 X = X 3 2 2 OH НО H₂C CH₂ H H configuration for C2: configuration for C3: b) . H₂C 3 Holly H 2 Br H CH₂ configuration for C2: configuration for C3: CH₂ Br 3 * 2 H₂C H configuration for C2: configuration for C3: Relationship between two species 2 3 configuration for C2: configuration for C3: 2 3 Br H₂C 2 Relationship between two species Br H H₂C 3 configuration for C2: configuration for C3: H 2 3 CH₂ OH Relationship between two species CH₂ Br configuration for C2: configuration for C3: 2 3 2 3 2 3

Chemistry
9th Edition
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Steven S. Zumdahl
Chapter7: Atomic Structure And Periodicity
Section: Chapter Questions
Problem 35Q: Does the minimization of electron-electron repulsions correlate with Hund's rule?
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Question

For each pair of structures shown, indicate whether the two species are constitutional isomers, enantiomers, diastereomers of one another, or identical molecules. Assign the absolute configuration of all molecules. Draw the Fisher projections for all molecules

H
Br
H₂C
b)
2
Br
3
configuration for C2:
configuration for C3:
H₂C
H
2
CH₂
configuration for C2:
configuration for C3:
OH
H₂C
2
3
* ±
2
3
HO
H
CH3
3
H
CH₂
2
configuration for C2:
configuration for C3:
3
H
X+
CH₂
2
H₂C
3
НО
Relationship between two species
configuration for C2:
configuration for C3:
Br
H
H₂C
3
H
2
Relationship between two species,
H₂C
Br
3
configuration for C2:
configuration for C3:
H
2
CH₂
3
OH
Relationship between two species
CH3
Br
configuration for C2:
configuration for C3:
2
3
2
3
2
3
Transcribed Image Text:H Br H₂C b) 2 Br 3 configuration for C2: configuration for C3: H₂C H 2 CH₂ configuration for C2: configuration for C3: OH H₂C 2 3 * ± 2 3 HO H CH3 3 H CH₂ 2 configuration for C2: configuration for C3: 3 H X+ CH₂ 2 H₂C 3 НО Relationship between two species configuration for C2: configuration for C3: Br H H₂C 3 H 2 Relationship between two species, H₂C Br 3 configuration for C2: configuration for C3: H 2 CH₂ 3 OH Relationship between two species CH3 Br configuration for C2: configuration for C3: 2 3 2 3 2 3
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