Reaction of CH3CH=CHC(O)C6H5 with 5 % Pd/C forms CH3CH2CH2C(O)C6H5 CH3CH(C6H5)CH2C(O)C6H5 CH3CH=CHCH2C6H5 CH3CH2CH2CH2C6H5 CH3CH2CH2C(OH)C6H5 as the product.
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- Oximene and myrcene, two hydrocarbons isolated from alfalfa that have the molecular formula C10H16, both yield 2,6- dimethyloctane when treated with H2 and a Pd catalyst. Ozonolysis of oximene forms (CH3)2C = O, CH2 = O, CH2(CHO)2, and CH3COCHO. Ozonolysis of myrcene yields (CH3)2C = O, CH2 = O, (two equiv), and HCOCH2CH2COCHO. Identify the structures of oximene and myrcene.reactions and products for C9H8O4 C9H8O4 + O2 --> C9H8O4 + H2O --> C9H8O4 + HCl --> C9H8O4 + OH- --> C9H8O4 + Na --> C9H8O4 + F -->Explain how the reaction of (CH3)2CHCH(Cl)CH3 with H2O yields two substitutionproducts, (CH3)2CHCH(OH)CH3 and (CH3)2C(OH)CH2CH3
- Rank the following groups in order of decreasing priority. −CH=CH2, −CH3, −C≡CH, −HWhat organic product is formed when 1‑methylcyclopentene is treated with NMMO in the presence of H2O and a catalytic amound of OsO4? Clearly show stereochemistry by drawing a wedge and dashed bond for each chiral carbon. Only draw one stereoisomer if more than one can be formed.When buta-1,3-diene (CH2 = CH – CH = CH2) is treated with HBr, two constitutional isomers are formed, CH3CHBrCH = CH2 and BrCH2CH = CHCH3. Draw a stepwise mechanism that accounts for the formation of both products.
- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent.a. HClb. CH3COClc. (CH3CO)2Od. excess CH3Ie. (CH3)2C = Of. CH3COCl, AlCl3g. CH3CO2Hh. NaNO2, HCli. Part (b), then CH3COCl, AlCl3j. CH3CHO, NaBH3CNRank the following groups in order of decreasing priority. a.−F, −NH2, −CH3, −OH b.−CH3, −CH2CH3, −CH2CH2CH3, −(CH2)3CH3 c.−NH2, −CH2NH2, −CH3, −CH2NHCH3 d.−COOH, −CH2OH, −H, −CHO e.−Cl, −CH3, −SH, −OH f.−C≡CH, −CH(CH3)2, −CH2CH3, −CH=CH2Rank the following groups in order of decreasing priority. −C≡CH, −CH(CH3)2, −CH2CH3, −CH=CH2
- Benzene is one of the compounds used as octane enhancers in unleaded gasoline. It is manufactured by thecatalytic conversion of acetylene to benzene: 3C2 H2(g) ⇌ C6 H6(g). Which value of Kc would make this reactionmost useful commercially? Kc ≈ 0.01, Kc ≈ 1, or Kc ≈ 10. Explain your answerDraw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reactionoccurs.a. H2 + Pd-Cb. H2 + Lindlar catalystc. Na, NH3d. CH3CO3He. [1] CH3CO3H; [2] H2O, HO–f. [1] OsO4 + NMO; [2] NaHSO3, H2Og. KMnO4, H2O, HO–h. [1] LiAlH4; [2] H2Oi. [1] O3; [2] CH3SCH3j. (CH3)3COOH, Ti[OCH(CH3)2]4, (–)-DETk. mCPBAl. Product in (k); then [1] LiAlH4; [2] H2OOrder the following substituents from highest priority to lowest priority: CH3, OH, H,F. Use the Cahn-Ingold-Prelog priority system. a. F, CH3, OH, H b. H, CH3, F, OH c. F, OH, CH3, H d. H, CH3, OH, F