c) Calculate the solubility (s) of BaSO4 (Ksp = 1.08×10-10)      in an aqueous solution with ionic strengths (Im) = 0.00010 mol kg-1. Given       that: A = 0.509 for aqueous solution at 25 oC. [1.09×10-5] (hint: MX ⇌ M+ + X-, ??sp = (??M+)(??X−), Ksp denotes solubility product)

Chemistry: Matter and Change
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Chapter14: Mixtures And Solutions
Section: Chapter Questions
Problem 92A
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c) Calculate the solubility (s) of BaSO4 (Ksp = 1.08×10-10)
     in an aqueous solution with ionic strengths (Im) = 0.00010 mol kg-1. Given       that: A = 0.509 for aqueous solution at 25 oC. [1.09×10-5]
(hint: MX ⇌ M+ + X-, ??sp = (??M+)(??X−), Ksp denotes solubility product)

in an aqueous solution with ionic strengths (Im) = 0.00010 mol kg1. Given that: A =
0.509 for aqueous solution at 25 °C. [1.09×10-5]
%3D
(hint: MX = M* + X', Ksp = (am+)(ax-), Ksp denotes solubility product)
Table 1 Limiting ionic conductivities (Ao) in water at 298 K
Cations
do (ms m? mol1)
Anions
Ao (ms m? mol4)
H+
34.96
OH
19.91
K+
7.35
co?
13.86
Lit
3.87
HCO,
5.46
NH4*
7.35
CH3CO,
4.09
H+
34.96
OH
19.91
Transcribed Image Text:in an aqueous solution with ionic strengths (Im) = 0.00010 mol kg1. Given that: A = 0.509 for aqueous solution at 25 °C. [1.09×10-5] %3D (hint: MX = M* + X', Ksp = (am+)(ax-), Ksp denotes solubility product) Table 1 Limiting ionic conductivities (Ao) in water at 298 K Cations do (ms m? mol1) Anions Ao (ms m? mol4) H+ 34.96 OH 19.91 K+ 7.35 co? 13.86 Lit 3.87 HCO, 5.46 NH4* 7.35 CH3CO, 4.09 H+ 34.96 OH 19.91
c) Calculate the solubility (s) of BaSO4 (Ksp = 1.08×10-1º)
%3D
Transcribed Image Text:c) Calculate the solubility (s) of BaSO4 (Ksp = 1.08×10-1º) %3D
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