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C symmetry with the s, p, and/or d me

C symmetry with the s, p, and/or d me

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 39P
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Match each ligand SALC symmetry with the s, p, and/or d metal orbital(s) with which it will interact. (The Generic Octahedral Metal Complex information above may be useful in doing this.) A1g V [ Choose ] p(x), p(y) p(x), p(y), p(z) Eg p(z) d(z^2), d(x^2-y^2) T2g p(y) d(xz), d(yz) p(x) T1u d(xy), d(xz), d(yz)
Transcribed Image Text:Match each ligand SALC symmetry with the s, p, and/or d metal orbital(s) with which it will interact. (The Generic Octahedral Metal Complex information above may be useful in doing this.) A1g V [ Choose ] p(x), p(y) p(x), p(y), p(z) Eg p(z) d(z^2), d(x^2-y^2) T2g p(y) d(xz), d(yz) p(x) T1u d(xy), d(xz), d(yz)
Some different views of an octahedral symmetry metal complex 1 1 3 6. 2 1 4 View down a C, axis View down a C, axis View down a C,axis E 8C, 6C, 6C, 3C, i On i 6S, 85, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Az8 1 1 -1 -1 1 Eg 2 z², x² - y? -1 0. -1 -1 -1 1 -1 -1 (xy, xz, yz) T2g -1 -1 1 1 -1 -1 A1u 1 1 1 -1 -1 -1 -1 A2u 1 -1 -1 1 -1 -1 -1 1 E -2 1 -2 -1 2 (x, y, z) -1 1 -1 -3 -1 1 3 T2u 1 -1 -1 -3 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 3. 3. 1. 2. 3. 1. 2)
Transcribed Image Text:Some different views of an octahedral symmetry metal complex 1 1 3 6. 2 1 4 View down a C, axis View down a C, axis View down a C,axis E 8C, 6C, 6C, 3C, i On i 6S, 85, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Az8 1 1 -1 -1 1 Eg 2 z², x² - y? -1 0. -1 -1 -1 1 -1 -1 (xy, xz, yz) T2g -1 -1 1 1 -1 -1 A1u 1 1 1 -1 -1 -1 -1 A2u 1 -1 -1 1 -1 -1 -1 1 E -2 1 -2 -1 2 (x, y, z) -1 1 -1 -3 -1 1 3 T2u 1 -1 -1 -3 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 3. 3. 1. 2. 3. 1. 2)
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