c) The enantioselectivity of the reaction is 97:3 er. Draw the minor enantiomer formed in this reaction.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.21P
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Need help with part c). Thank you :)

Shown below is the proline catalysed reaction of A and B to give ketone C.
CO2H
Br
15 mol%
HN°
proline
A
42 hours
CH3
CH3
Ph
Ph
В
С, 92% yield, 97:3 er
a) Calculate the turnover number for this reaction, show your working.
b) Calculate the turnover frequency for this reaction, show your working.
c) The enantioselectivity of the reaction is 97:3 er. Draw the minor enantiomer formed in this
reaction.
Transcribed Image Text:Shown below is the proline catalysed reaction of A and B to give ketone C. CO2H Br 15 mol% HN° proline A 42 hours CH3 CH3 Ph Ph В С, 92% yield, 97:3 er a) Calculate the turnover number for this reaction, show your working. b) Calculate the turnover frequency for this reaction, show your working. c) The enantioselectivity of the reaction is 97:3 er. Draw the minor enantiomer formed in this reaction.
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