Name the type of reaction and provide a possible reagent assign all the stereocentres found in the compounds via cahn ingold prelog rulesdefine the relation between compound. D E F Gidentify the 2 stereoisomers likely to be formed in compound c Compound C undergoes a chemical reaction with a reagent, resulting in the formationof two new compounds. Four potential stereoisomers of the product are shown below.O.OHO.OHOHOHCompound DCompound ECompound FCompound G Compound C show below is the starting material used in a chemical reaction.Compound C

Compound C contains two functional groups ; Carbonyl /ketone and ether. Compounds D, E, F and G…

Name the type of reaction and provide a possible reagent assign all the stereocentres found in the compounds via cahn ingold prelog rules define the relation between compound. D E F G identify the 2 stereoisomers likely to be formed in compound c

Name the type of reaction and provide a possible reagent assign all the stereocentres found in the compounds via cahn ingold prelog rules define the relation between compound. D E F G identify the 2 stereoisomers likely to be formed in compound c

Chemistry for Today: General, Organic, and Biochemistry

9th Edition

ISBN:9781305960060

Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen

Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen

Chapter12: Unsaturated Hydrocarbons

Section: Chapter Questions

Problem 12.4E

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

Name the type of reaction and provide a possible reagent

assign all the stereocentres found in the compounds via cahn ingold prelog rules

define the relation between compound. D E F G

identify the 2 stereoisomers likely to be formed in compound c

Compound C undergoes a chemical reaction with a reagent, resulting in the formation
of two new compounds. Four potential stereoisomers of the product are shown below.
O.
OH
O.
OH
OH
OH
Compound D
Compound E
Compound F
Compound G

Compound C show below is the starting material used in a chemical reaction.
Compound C

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Cromolyn sodium, developed in the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercise-induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. Cromolyn sodium is synthesized in the following series of steps. Treatment of one mole of epichlorohydrin with two moles of 2,6-dihydroxyacetophenone in the presence of base gives I. Treatment of I with two moles of diethyl oxalate in the presence of sodium ethoxide gives a diester II. Saponification of the diester with aqueous NaOH gives cromolyn sodium. Q.Propose a mechanism for the formation of compound I.
Cromolyn sodium, developed in the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercise-induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. Cromolyn sodium is synthesized in the following series of steps. Treatment of one mole of epichlorohydrin with two moles of 2,6-dihydroxyacetophenone in the presence of base gives I. Treatment of I with two moles of diethyl oxalate in the presence of sodium ethoxide gives a diester II. Saponification of the diester with aqueous NaOH gives cromolyn sodium. Q.Propose a structural formula for compound II and a mechanism for its formation.
Cromolyn sodium, developed in the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercise-induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. Cromolyn sodium is synthesized in the following series of steps. Treatment of one mole of epichlorohydrin with two moles of 2,6-dihydroxyacetophenone in the presence of base gives I. Treatment of I with two moles of diethyl oxalate in the presence of sodium ethoxide gives a diester II. Saponification of the diester with aqueous NaOH gives cromolyn sodium. Q. Is cromolyn sodium chiral? If so, which of the possible stereoisomers are formed in this synthesis?
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