C. Determination of Cell Potentials Cell Notation (Galvanic) Zn | Zn²+ (0.10 M) || Cu²+ (0.10 M) | Cu Cu | Cu²+ (0.10 M) || Fe³+ (0.10 M), Fe²+ (0.10 M) | C Cu | Cu²+ (0.10 M) || Br₂ (x M), Br (0.10 M) | C Cu | Cu²+ (0.10 M) || 12 (x M), I¯ (0.10 M) | C Cu | Cu²+ (0.01 M) || Cu²+ (0.10 M) | Cu Cu | NH3 (0.533 M), [Cu(NH3)4²†] (0.033 M) || Cu²+ (0.10 M) | Cu Ecell,expt (V) Ecell,theo (V) % error

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter21: Potentiometry
Section: Chapter Questions
Problem 21.23QAP
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Answer the ecell value only

Electrochemical Cells
Zn|Zn²+ (0.10 M) || Cu²+ (0.10 M)| Cu
Cu|Cu²+ (0.10 M) || Fe³+ (0.10 M), Fe²+ (0.10 M)|C
Cu Cu²+ (0.10 M) || Br₂ (x M), Br (0.10 M)|C
Cu Cu²+ (0.10 M) || 1₂ (x M), I- (0.10 M)|C
Cu Cu²+ (0.01 M) || Cu²+ (0.10 M) Cu
Cu|NH3 (0.533 M), [Cu(NH3)4²+] (0.033 M) || Cu²+ (0.10 M)|Cu
Measured Potential (V)
1.095
0.450
0.710
0.260
0.031
0.370
Transcribed Image Text:Electrochemical Cells Zn|Zn²+ (0.10 M) || Cu²+ (0.10 M)| Cu Cu|Cu²+ (0.10 M) || Fe³+ (0.10 M), Fe²+ (0.10 M)|C Cu Cu²+ (0.10 M) || Br₂ (x M), Br (0.10 M)|C Cu Cu²+ (0.10 M) || 1₂ (x M), I- (0.10 M)|C Cu Cu²+ (0.01 M) || Cu²+ (0.10 M) Cu Cu|NH3 (0.533 M), [Cu(NH3)4²+] (0.033 M) || Cu²+ (0.10 M)|Cu Measured Potential (V) 1.095 0.450 0.710 0.260 0.031 0.370
C. Determination of Cell Potentials
Cell Notation (Galvanic)
Zn | Zn²+ (0.10 M) || Cu²+ (0.10 M) | Cu
Cu | Cu²+ (0.10 M) || Fe³+ (0.10 M), Fe²+ (0.10 M) | C
Cu | Cu²+ (0.10 M) || Br₂ (x M), Br (0.10 M) | C
Cu | Cu²+ (0.10 M) || 12 (x M), I¯ (0.10 M) | C
Cu | Cu²+ (0.01 M) || Cu²+ (0.10 M) | Cu
Cu | NH3 (0.533 M), [Cu(NH3)4²*] (0.033 M) || Cu²+ (0.10 M) | Cu
Ecell,expt
(V)
Ecell, theo
(V)
% error
Transcribed Image Text:C. Determination of Cell Potentials Cell Notation (Galvanic) Zn | Zn²+ (0.10 M) || Cu²+ (0.10 M) | Cu Cu | Cu²+ (0.10 M) || Fe³+ (0.10 M), Fe²+ (0.10 M) | C Cu | Cu²+ (0.10 M) || Br₂ (x M), Br (0.10 M) | C Cu | Cu²+ (0.10 M) || 12 (x M), I¯ (0.10 M) | C Cu | Cu²+ (0.01 M) || Cu²+ (0.10 M) | Cu Cu | NH3 (0.533 M), [Cu(NH3)4²*] (0.033 M) || Cu²+ (0.10 M) | Cu Ecell,expt (V) Ecell, theo (V) % error
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