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Calculate AG° for the reaction of iron(lII) oxide with carbon monoxide to give elemental iron and carbon dioxide. Use data in the table below: Standard Entropies of Some Typical Substances at 298.15 K Substance (I mol- K-1) (I mol-' K-1) U mol- K-1) Substance N2(g) NH3(g) Substance Ag() AGCI(s) 42.55 CaO(G) 40 191.5 96.2 Ca(OH)2() 76.1 192.5 28.3 CaSO,() CaSO, H,O(;) CaSO4 2H¿0(;) C2(g) Al() 107 NH,CI() 94.6 NO(g) NO:(g) N,0(g) Al,O3() 51.0 131 210.6 C) (graphite) CO(g) CO;(g) CH,(g) 5.69 194.0 240.5 197.9 223.0 220.0 213.6 Fe(s) 27 N,O,(g) 304 Fe,Og(0) H;(g) H;O(g) 186.2 90.0 Na(s) 51.0 CH;CI(g) CH,OH(/) CO(NH),() CO(NH;),(aq) C;H2(g) C,H,(g) C,H&g) 234.2 Na,CO3(;) NaHCO,() 130.6 136 126.8 188.7 102 H,O(/) HCI(g) HNO,(1) H,SO,(1) HC,H,O;(/) Hg(/) Hg(g) 104.6 69.96 NaCI() 72.38 173.8 186.7 NaOH(,) 64.18 NazSO4(s) O2(g) 200.8 155.6 149.4 219.8 157 205.0 229.5 160 PbO(1) 67.8 C,H13() C,H,OH(/) S() SO-(g) SO:(g) 466.9 76.1 31.9 161 175 248.5 Ca(s) 41.4 K(s) 64.18 256.2 CACO,() 92.9 KC(,) 82.59 CaCl,() 114 K,SO(6) 176

Calculate AG° for the reaction of iron(lII) oxide with carbon monoxide to give elemental iron and carbon dioxide. Use data in the table below: Standard Entropies of Some Typical Substances at 298.15 K Substance (I mol- K-1) (I mol-' K-1) U mol- K-1) Substance N2(g) NH3(g) Substance Ag() AGCI(s) 42.55 CaO(G) 40 191.5 96.2 Ca(OH)2() 76.1 192.5 28.3 CaSO,() CaSO, H,O(;) CaSO4 2H¿0(;) C2(g) Al() 107 NH,CI() 94.6 NO(g) NO:(g) N,0(g) Al,O3() 51.0 131 210.6 C) (graphite) CO(g) CO;(g) CH,(g) 5.69 194.0 240.5 197.9 223.0 220.0 213.6 Fe(s) 27 N,O,(g) 304 Fe,Og(0) H;(g) H;O(g) 186.2 90.0 Na(s) 51.0 CH;CI(g) CH,OH(/) CO(NH),() CO(NH;),(aq) C;H2(g) C,H,(g) C,H&g) 234.2 Na,CO3(;) NaHCO,() 130.6 136 126.8 188.7 102 H,O(/) HCI(g) HNO,(1) H,SO,(1) HC,H,O;(/) Hg(/) Hg(g) 104.6 69.96 NaCI() 72.38 173.8 186.7 NaOH(,) 64.18 NazSO4(s) O2(g) 200.8 155.6 149.4 219.8 157 205.0 229.5 160 PbO(1) 67.8 C,H13() C,H,OH(/) S() SO-(g) SO:(g) 466.9 76.1 31.9 161 175 248.5 Ca(s) 41.4 K(s) 64.18 256.2 CACO,() 92.9 KC(,) 82.59 CaCl,() 114 K,SO(6) 176

Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section16.5: Entropy And The Second Law Of Thermodynamics
Problem 16.8E
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Calculate ∆G° for the reaction of iron(III) oxide with carbon monoxide to give elemental iron and carbon dioxide.

Use data in the table below:

Calculate AG° for the reaction of iron(III) oxide with carbon monoxide to give elemental iron and carbon dioxide. Use data in the table below: Standard Entropies of Some Typical Substances at 298.15 K (U mol- K-1) (I mol- K-1) (I mol-' K-1) Substance Substance Substance Ag() AgCI(s) 42.55 CaO(s) 40 N2(g) NH3(g) 191.5 96.2 Ca(OH),() 76.1 192.5 Al() 28.3 107 NH,CI() 94.6 Al,O;(;) C) (graphite) CO(g) CO-(g) CHĄ(g) CH,CI(g) CH,OH(/) CaSO, H,0() CaSO4- 2H,O(;) NO(g) NO:(g) N,0(g) 51.0 131 210.6 5.69 194.0 240.5 Ch(g) Fe(s) 197.9 223.0 220.0 213.6 27 N,0,(g) 304 186.2 Fe,O3(;) H,(g) H;O(g) 90.0 Na(s) 51.0 234.2 130.6 Na,CO3() 136 126.8 188.7 NaHCO3(;) 102 CO(NH,),() 104.6 H,O(/) 69.96 NaCI() 72.38 CO(NH),(aq) 173.8 HCI(g) 186.7 NaOH() 64.18 C,H2(g) C,H(g) C,H(g) 200.8 HNO3(1) 155.6 NazSO4(s) 149.4 219.8 H,SO,() 157 0:(g) 205.0 229.5 HC,H;O;(1) 160 PbO(;) 67.8 466.9 Hg(/) Hg(g) 76.1 S() 31.9 SO,(g) SO3(g) C,H,OH() 161 175 248.5 Ca(s) 41.4 K(s) 64.18 256.2 CACO,() 92.9 KCI(,) 82.59 CaCl,() 114 K,SO,() 176
Transcribed Image Text:Calculate AG° for the reaction of iron(III) oxide with carbon monoxide to give elemental iron and carbon dioxide. Use data in the table below: Standard Entropies of Some Typical Substances at 298.15 K (U mol- K-1) (I mol- K-1) (I mol-' K-1) Substance Substance Substance Ag() AgCI(s) 42.55 CaO(s) 40 N2(g) NH3(g) 191.5 96.2 Ca(OH),() 76.1 192.5 Al() 28.3 107 NH,CI() 94.6 Al,O;(;) C) (graphite) CO(g) CO-(g) CHĄ(g) CH,CI(g) CH,OH(/) CaSO, H,0() CaSO4- 2H,O(;) NO(g) NO:(g) N,0(g) 51.0 131 210.6 5.69 194.0 240.5 Ch(g) Fe(s) 197.9 223.0 220.0 213.6 27 N,0,(g) 304 186.2 Fe,O3(;) H,(g) H;O(g) 90.0 Na(s) 51.0 234.2 130.6 Na,CO3() 136 126.8 188.7 NaHCO3(;) 102 CO(NH,),() 104.6 H,O(/) 69.96 NaCI() 72.38 CO(NH),(aq) 173.8 HCI(g) 186.7 NaOH() 64.18 C,H2(g) C,H(g) C,H(g) 200.8 HNO3(1) 155.6 NazSO4(s) 149.4 219.8 H,SO,() 157 0:(g) 205.0 229.5 HC,H;O;(1) 160 PbO(;) 67.8 466.9 Hg(/) Hg(g) 76.1 S() 31.9 SO,(g) SO3(g) C,H,OH() 161 175 248.5 Ca(s) 41.4 K(s) 64.18 256.2 CACO,() 92.9 KCI(,) 82.59 CaCl,() 114 K,SO,() 176
Standard Enthalpies of Formation of Typical Substances AH; (kJ mol-1) Substance AH; (kJ mol-1) Substance Ag(s) H,O;(1) - 187.6 AgBr(;) - 100.4 HBr(g) -36 AGCI() -127.0 HCI(g) -92.30 Al(s) HI(g) HNO,(/) H,SO,(!) 26.6 Al,O;(6) - 1669.8 - 173.2 C) (graphite) -811.32 CO(g) -110.5 HC,H;O;(/) -487.0 CO:(g) CHĄ(g) CH;CI(g) CH,I(g) CH;OH(/) -393.5 Hg(!) -74.848 Hg(g) 60.84 -82.0 14.2 K(3) - 238.6 KCI() -435.89 CO(NH,),() (urca) -333.19 K,SO,(1) - 1433.7 CO(NH),(aq) - 391.2 N;(g) NH3(g) NH,CI(}) NO(g) NO,(g) N,0(g) N,O,(g) N,O;(g) CH2(g) 226.75 -46.19 C,H4(g) CH(g) C,H,OH(/) 52.284 -315.4 -84.667 90.37 -277.63 33.8 Ca(s) 81.57 CaBrz(s) CACO3(s) -682.8 9.67 - 1207 11 CaC2(s) -795.0 Na(s) CaO(s) -635.5 NaHCO,() -947.7 Ca(OH)2(s) -986.59 Na,CO3(;) -1131 CaSO,() -1432.7 NaCI(s) -411.0 CaSO, H,0() CaSO,- 2H,O(s) Cl,(g) - 1575.2 NAOH() -426.8 - 2021.1 Na,SO,(s) - 1384.5 0;(g) Pb(s) Fe(s) Fe,O3(;) -822.2 PbO(s) -219.2 H(g) S() SO:(g) H;O(g) H;O() -241.8 - 296.9 -285.9 SO;(g) -395.2 AG° = i kJ
Transcribed Image Text:Standard Enthalpies of Formation of Typical Substances AH; (kJ mol-1) Substance AH; (kJ mol-1) Substance Ag(s) H,O;(1) - 187.6 AgBr(;) - 100.4 HBr(g) -36 AGCI() -127.0 HCI(g) -92.30 Al(s) HI(g) HNO,(/) H,SO,(!) 26.6 Al,O;(6) - 1669.8 - 173.2 C) (graphite) -811.32 CO(g) -110.5 HC,H;O;(/) -487.0 CO:(g) CHĄ(g) CH;CI(g) CH,I(g) CH;OH(/) -393.5 Hg(!) -74.848 Hg(g) 60.84 -82.0 14.2 K(3) - 238.6 KCI() -435.89 CO(NH,),() (urca) -333.19 K,SO,(1) - 1433.7 CO(NH),(aq) - 391.2 N;(g) NH3(g) NH,CI(}) NO(g) NO,(g) N,0(g) N,O,(g) N,O;(g) CH2(g) 226.75 -46.19 C,H4(g) CH(g) C,H,OH(/) 52.284 -315.4 -84.667 90.37 -277.63 33.8 Ca(s) 81.57 CaBrz(s) CACO3(s) -682.8 9.67 - 1207 11 CaC2(s) -795.0 Na(s) CaO(s) -635.5 NaHCO,() -947.7 Ca(OH)2(s) -986.59 Na,CO3(;) -1131 CaSO,() -1432.7 NaCI(s) -411.0 CaSO, H,0() CaSO,- 2H,O(s) Cl,(g) - 1575.2 NAOH() -426.8 - 2021.1 Na,SO,(s) - 1384.5 0;(g) Pb(s) Fe(s) Fe,O3(;) -822.2 PbO(s) -219.2 H(g) S() SO:(g) H;O(g) H;O() -241.8 - 296.9 -285.9 SO;(g) -395.2 AG° = i kJ
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