Calculate the pH at each of the following points for the titration of 100 mL of 0. 6 M dl-Histidine with the following volumes  of 1.20 M sodium hydroxide.   H3His  ↔  H+  + H2His-          Ka1 = 3.98x10-3 H2His- ↔  H+  +  HHis2-         Ka2 = 9.12x10-7 HHis2- ↔  H+  +  His3-            Ka3 = 4.67x10-10   Vol. of NaOH Calculated pH 0 mL     30 mL     50 mL     75 mL     100 mL     125 mL     135 mL     150 mL     175 mL       Please provide a sketch of the titration curve and label both the x & y axis and applicable equations used at each data point (e.g., pH = - log[H+] or pH = pKa or pH = pKa + log  )

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter14: Principles Of Neutralization Titrations
Section: Chapter Questions
Problem 14.9QAP
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Calculate the pH at each of the following points for the titration of 100 mL of 0. 6 M dl-Histidine with the following volumes  of 1.20 M sodium hydroxide.

 

H3His  ↔  H+  + H2His-          Ka1 = 3.98x10-3

H2His- ↔  H+  +  HHis2-         Ka2 = 9.12x10-7

HHis2- ↔  H+  +  His3-            Ka3 = 4.67x10-10

 

Vol. of NaOH

Calculated pH

0 mL

 

 

30 mL

 

 

50 mL

 

 

75 mL

 

 

100 mL

 

 

125 mL

 

 

135 mL

 

 

150 mL

 

 

175 mL

 

 

 

Please provide a sketch of the titration curve and label both the x & y axis and applicable equations used at each data point (e.g., pH = - log[H+or pH = pKa or pH = pKa + log  )

 

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