Calculate the value of cp at 298 K and 1 atm pressure predicted for Cl, and NO, by the classical equipartition theorem. (Enter your answers to at least two decimal places.) Cy(Cl,) = J mol K (NO,) - J mol K The actual heat capacities of C, and NO, are 33.91 and 36.97 J mol' K', respectively. Calculate the fraction (expressed as a percentage) of the measured value that arises from vibrational motions. vibrational contribution to cp(Cl,) vibrational contribution to cp(NO,) = 9%

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter12: Thermodynamic Processes And Thermochemistry
Section: Chapter Questions
Problem 67AP
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Calculate the value of cp at 298 K and 1 atm pressure predicted for Cl, and NO, by the classical equipartition theorem. (Enter your
answers to at least two decimal places.)
Cp(Cl)) =
J mol 1 K1
Cp(NO,) =
J mol K1
The actual heat capacities of C and NO, are 33.91 and 36.97 J molK, respectively. Calculate the fraction (expressed as a
percentage) of the measured value that arises from vibrational motions.
vibrational contribution to cp(Cl,) =
vibrational contribution to cp(NO,) =
Transcribed Image Text:Calculate the value of cp at 298 K and 1 atm pressure predicted for Cl, and NO, by the classical equipartition theorem. (Enter your answers to at least two decimal places.) Cp(Cl)) = J mol 1 K1 Cp(NO,) = J mol K1 The actual heat capacities of C and NO, are 33.91 and 36.97 J molK, respectively. Calculate the fraction (expressed as a percentage) of the measured value that arises from vibrational motions. vibrational contribution to cp(Cl,) = vibrational contribution to cp(NO,) =
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