Can someone draw the mechanism for the pericyclic mechanism and explain the stereochemistry?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
Section: Chapter Questions
Problem 30CTQ: According to the conventions above, what is the sign ( + or ) of the P.E. change (H) for Rxn 3?
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Can someone draw the mechanism for the pericyclic mechanism and explain the stereochemistry?

Ar
Ar
co,CH, ncoc-Cmc-CoCH,
H
H,CO,C N CO,CH, 100°C
H,COČ-C=C-COCH,
H,CO,C
H
H
H
Ar
(19)
H
Co,CH,
hv
H,CO,C
H.
H,CO,C
Co,CH,
hv
Transcribed Image Text:Ar Ar co,CH, ncoc-Cmc-CoCH, H H,CO,C N CO,CH, 100°C H,COČ-C=C-COCH, H,CO,C H H H Ar (19) H Co,CH, hv H,CO,C H. H,CO,C Co,CH, hv
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