,CH3 CH2 Isomerizahon HBr Pd Br H3C H3 C 2 - butene 1- bromo butene 1- bulene No HC E CH Cr. 0, / H, O2 CH3 , (excess), Pd /C H,C Heat, 600° C

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter31: Introduction To Analytical Separations
Section: Chapter Questions
Problem 31.29QAP
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Provide a complete arrow push mechanism for each of the following reactions

CH3
CH2
Isomerizahon
Pd
Br
H3C
H3 C
2 - butene
1- bulene
1 - bromo butene
No HC = CH
Cr.0s / H, O,
600° C
CH3
H, Cexcess), Pd/C
H,C
Heat,
hexane
benzene
CH3
CH3
H3C
CI
NBS
Br
AICI3
ethyl benzene
(1-bromoethyl) benzene
HO
CH2
KOH
1. 8H3/THF
2. H, 02
ethenylbenzene
2- phenylethan -1-ol
HN
PCC
NH3
2-phenylacetol dehyde
2- phenylethan- 1 - imine
CS Scanned with CamScanner
Transcribed Image Text:CH3 CH2 Isomerizahon Pd Br H3C H3 C 2 - butene 1- bulene 1 - bromo butene No HC = CH Cr.0s / H, O, 600° C CH3 H, Cexcess), Pd/C H,C Heat, hexane benzene CH3 CH3 H3C CI NBS Br AICI3 ethyl benzene (1-bromoethyl) benzene HO CH2 KOH 1. 8H3/THF 2. H, 02 ethenylbenzene 2- phenylethan -1-ol HN PCC NH3 2-phenylacetol dehyde 2- phenylethan- 1 - imine CS Scanned with CamScanner
NH2
Na CN
HCL, H:0
H,0
CN
COCH
2-amino-3-phenyl propanitrile
phenylalanine
NH2
COH
02
H20
Iodinase
C00H
NH 2
H3C
H3C
tyrosine
MIT
COOH
NH2
H3C
DIT
но
Coupling of lodinoted tynsine
COOH
Thyroxine
CS Scanned with CamScanner
Transcribed Image Text:NH2 Na CN HCL, H:0 H,0 CN COCH 2-amino-3-phenyl propanitrile phenylalanine NH2 COH 02 H20 Iodinase C00H NH 2 H3C H3C tyrosine MIT COOH NH2 H3C DIT но Coupling of lodinoted tynsine COOH Thyroxine CS Scanned with CamScanner
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