CHCHOHH Y Y is 44. H,C A. Methylethanoate B. Ethylpropanoate C. Ethylethanoate D. Ethylmethanoate OH 45. Which of the following molecules does not possess enantiomers? A. CH,CH,CH,CO.H B. CHCIBICHOHCOOH C. CH,- CHCH,Br D. CH CIC(CH,)CO,H OH 46. The systematic name of CH,COCH,OH is A. hydroxypropanal B. 3-hydroxypropanal C. 3-hydroxypropanone D. Ketopropanol

Organic Chemistry
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Chapter22: Carbonyl Alpha-substitution Reactions
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Answer Q 44, 45 & 46 showing clearly all working and detailed explanations

35 The product formed when an acythalide
reacts with ammonia is?
A) an ester
C) an amide
Questions 42 and 43
os of
CHCOOH CH.COCI CH,COOC,H.
B) a nitrile
D) an amine nitrile solt
36. Give the reagents nece for the
0-C
G.
p. 1-C
42
Give the reagents and reaction conditions
for the conversion of I to Ii
A) SOCI, at room temperature
B) CI, in U.V light
C) HCI(aq)
D) FeCl (aq) / heat
following conversion
CH,CH CH, C-N,
E TWO
CH CH CH, NH,
A) NH,
C) NaOH/Br,
stion
ARIONS
s of
8) HOBr.
43. Give the reagents and reaction conditions
D) NaOH
37. Which one of the following reagents is
for the conversion of II to lHH
d of n
A) 2CH,CH,OH/H/ heat
B), phenoUNaOH(aq)
most suitable for converting of
ich is
C) hexanol/H
OH
CI-C-C.
into
ot at
D) benzoic acid/H
Cures tions
st of
YOH
A) PCL at 50°C
B) SOĆI, at room temperature
C) conc. HCI at 80°C
D) CI, in bright sunlight at 100°C
38. Which of the folowing is the main organic
product when BrCH COBr is treated with
cold water?
A) HOCH COBr
C) HOCH COOH
chdmystr
A)
44
CHCHOHH Y, Y is
HC
OH
A. Methylethanoate
B. Ethylpropanoate
C. Elhylethanoate
D. Ethylmethanoate
Choose
equired
50 RO
S R
B) BRCH,CO H
45. Which of the following molecules does not
possess enantiomers?
A. CH,CH CH CO.H
B. CHCIBICHOHCOOH
C. CH, - CHCH Br
D. CH CIC(CH,)cO.H
он
D) HOCH CHO
39. Which of the following compounds will
react with the product of its own oxidation
to form a sweet smelling liquid?
A) butanai
B) butan -1-ol
C) butan - 2- ol
D) butanoic acid
CHC
46. The systematic name of CH,COCH OH is
A. hydroxypropanal
B. 3-hydroxypropanal
C. 3-hydroxypropanone
D. Ketopropanol
40.
The compound with formula C,HO, exhibit
isomerism. What type of isomerism is
exhibitted by this compound?
A) stereoisomerism
B) functional group isomerism
C) structural isomerism
D) optical isomerism
41. The boiling points of carbonyls
compounds are
A) higher than those of carboxylic acid of
47. The saponification of ester of palmitic acid
(C„H, COOH) produces
A. Soap, glycerol and water
B. Glycerol and soap
C. Soap and water
D. A salt and a soap
same number of carbon atoms
B) lower than those of carboxylic acid of
same number of carbon atoms
C) same as those of carboxylic acid of
48.
The acid of molecular formula CHO, is
isomeric to
same number of carbon atoms
A A diol
D) none of the above.
C Anhydride
B
Ester
D.
Hydroxyleiher
356
Transcribed Image Text:35 The product formed when an acythalide reacts with ammonia is? A) an ester C) an amide Questions 42 and 43 os of CHCOOH CH.COCI CH,COOC,H. B) a nitrile D) an amine nitrile solt 36. Give the reagents nece for the 0-C G. p. 1-C 42 Give the reagents and reaction conditions for the conversion of I to Ii A) SOCI, at room temperature B) CI, in U.V light C) HCI(aq) D) FeCl (aq) / heat following conversion CH,CH CH, C-N, E TWO CH CH CH, NH, A) NH, C) NaOH/Br, stion ARIONS s of 8) HOBr. 43. Give the reagents and reaction conditions D) NaOH 37. Which one of the following reagents is for the conversion of II to lHH d of n A) 2CH,CH,OH/H/ heat B), phenoUNaOH(aq) most suitable for converting of ich is C) hexanol/H OH CI-C-C. into ot at D) benzoic acid/H Cures tions st of YOH A) PCL at 50°C B) SOĆI, at room temperature C) conc. HCI at 80°C D) CI, in bright sunlight at 100°C 38. Which of the folowing is the main organic product when BrCH COBr is treated with cold water? A) HOCH COBr C) HOCH COOH chdmystr A) 44 CHCHOHH Y, Y is HC OH A. Methylethanoate B. Ethylpropanoate C. Elhylethanoate D. Ethylmethanoate Choose equired 50 RO S R B) BRCH,CO H 45. Which of the following molecules does not possess enantiomers? A. CH,CH CH CO.H B. CHCIBICHOHCOOH C. CH, - CHCH Br D. CH CIC(CH,)cO.H он D) HOCH CHO 39. Which of the following compounds will react with the product of its own oxidation to form a sweet smelling liquid? A) butanai B) butan -1-ol C) butan - 2- ol D) butanoic acid CHC 46. The systematic name of CH,COCH OH is A. hydroxypropanal B. 3-hydroxypropanal C. 3-hydroxypropanone D. Ketopropanol 40. The compound with formula C,HO, exhibit isomerism. What type of isomerism is exhibitted by this compound? A) stereoisomerism B) functional group isomerism C) structural isomerism D) optical isomerism 41. The boiling points of carbonyls compounds are A) higher than those of carboxylic acid of 47. The saponification of ester of palmitic acid (C„H, COOH) produces A. Soap, glycerol and water B. Glycerol and soap C. Soap and water D. A salt and a soap same number of carbon atoms B) lower than those of carboxylic acid of same number of carbon atoms C) same as those of carboxylic acid of 48. The acid of molecular formula CHO, is isomeric to same number of carbon atoms A A diol D) none of the above. C Anhydride B Ester D. Hydroxyleiher 356
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