yニ,ニ N P 'CI HO, Q んこんこんn S R to `Br

Living By Chemistry: First Edition Textbook
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ChapterU1: Alchemy: Matter, Atomic Structure, And Bonding
Section: Chapter Questions
Problem SV1RQ
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Question

The following scheme shows the retrosynthetic analysis of 1-isopentylaziridine to form
series of intermediates via Functional Group Inversion (FGI). Choose the correct reagents
of N-S for the respective conversion from the given list of reagents.

yニ,ニ
N
P
'CI
HO,
Q
んこんこんn
S
R
to
`Br
Transcribed Image Text:yニ,ニ N P 'CI HO, Q んこんこんn S R to `Br
List of reagents
HN.
1) BH3/THF
2) H2О2, ОН
CIHN
1) Hg(OAc)2, H2O
2) NABH4
KOt-CH2CH2CH2CH3,
SOC22
heat
1) NaBH4
2) H2O
1) LİAIH4
2) H2O
NaOCH3, heat
1) PC14, CC14
H2CrO4, H2O
РСС, СН2C12
Transcribed Image Text:List of reagents HN. 1) BH3/THF 2) H2О2, ОН CIHN 1) Hg(OAc)2, H2O 2) NABH4 KOt-CH2CH2CH2CH3, SOC22 heat 1) NaBH4 2) H2O 1) LİAIH4 2) H2O NaOCH3, heat 1) PC14, CC14 H2CrO4, H2O РСС, СН2C12
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