Chemistry An EDTA solution was prepared by dissolving 2 g of the salt in 0.500 L of water. Aliquots of 50 ml of the primary standard MgCO3 containing 0.7682 g/L were titrated consuming an average of 43.25 ml of EDTA in the titration. Å mineral water sample was analyzed by consuming 18.81 ml of the titrant afterwards. Determine: a. EDTA concentration b. ppm CaCo3

Chemistry An EDTA solution was prepared by dissolving 2 g of the salt in 0.500 L of water. Aliquots of 50 ml of the primary standard MgCO3 containing 0.7682 g/L were titrated consuming an average of 43.25 ml of EDTA in the titration. Å mineral water sample was analyzed by consuming 18.81 ml of the titrant afterwards. Determine: a. EDTA concentration b. ppm CaCo3

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter31: Introduction To Analytical Separations

Section: Chapter Questions

Problem 31.21QAP

See similar textbooks

Similar questions

As part of a geological team that studied a local cave, you brought with you a bunch of 1.00 g rock samples to be studied. Each rock was prepared and titrated against 0.050 M EDTA. a. Calculate the percent calcite (CaCO3) content of rock A if it was titrated with 48.0 mL EDTA
A 3.25 g sample of an iron-containing mineral was dissolved in an acid medium and calibrated to 500 mL. A 25.00 mL aliquot was titrated with 0.0025 M KMnO4 spending a volume of 9.32 mL. Subsequently, a 25.00 mL aliquot was passed through a Walden reducer to later titrate it with the same permanganate solution, using a volume of 14.15 mL for the titration. Determine the percentage of Fe(III) in the sample and report it as % Fe2O3
A 3.7145 g portion of disodium EDTA dihydrate (M.W. 372.24) was dissolved in enoughdistilled water of prepare 1.000 L of solution. A 100.0 mL water sample was adjusted topH 10 and titrated to the Eriochrome Black T end point with 11.23 mL of the EDTAsolution. When the pH of another 100.0 mL water sample was adjusted to pH 12 andtitrated with EDTA, 2.11 mL of titrant was required. Calculate the concentration of Ca(II)and Mg(II) in the water. Express the answers in mg/L of CaCl2 and MgSO 4 , respectively.
For complexometric titration of Ca (II) ions in the shell of an egg sample weighing 59,427 g, the necessary processes were applied to the egg shells and a sample of 100 mL was prepared. From the prepared sample, 1 mL was taken and diluted to 100 mL, the pH was adjusted, and two drops of EBT indicator were dripped on it. The prepared solution was titrated with 27.4 mL of EDTA solution set at 0.0097 M. Calculate the amount of calcium in the sample in CaCO3%. (Ca = 40g / mol, CaCO3= 100g / mol)
A 4.912-g sample of a petroleum product was burnedin a tube furnace, and the SO2produced was collectedin 3% H2O2.Reaction:SO2(g)+H2O2→H2SO4A 25.00-mL portion of 0.00873 M NaOH was introducedinto the solution of H2SO4, following whichthe excess base was back-titrated with 15.17 mL of0.01102 M HCl. Calculate the sulfur concentrationin the sample in parts per million.
The sulfur content of insoluble sulfides that do not readilydissolve in acid can be measured by oxidation with Br2to SO42.25Metal ions are then replaced with Hby an ion-exchange column,and sulfate is precipitated as BaSO4with a known excess ofBaCl2. The excess Ba2is then titrated with EDTA to determinehow much was present. (To make the indicator end point clearer,a small, known quantity of Zn2also is added. The EDTA titratesboth the Ba2and the Zn2.) Knowing the excess Ba2, we cancalculate how much sulfur was in the original material. To analyzethe mineral sphalerite (ZnS, FM 97.46), 5.89 mg of powderedsolid were suspended in a mixture of CCl4and H2O containing1.5 mmol Br2. After 1 h at 20 C and 2 h at 50 C, the powder dis-solved and the solvent and excess Br2were removed by heating.The residue was dissolved in 3 mL of water and passed throughan ion-exchange column to replace Zn2with H. Then 5.000 mLof 0.014 63 M BaCl2were added to precipitate all sulfate as BaSO4.After the addition of…
A 14.92 g sample of bacon is pureed in a blender with 100.0 mL of water. The suspension is filtered and the clear solution containing dissolved sodium nitrite is adjusted to pH 2. The solution is treated with 25.0 mL of 0.0150 M KMnO4 to oxidize the nitrite to nitrate and after standing for 10 minutes, the excess KMnO4 is back titrated with 15.0 mL of 0.0818 M FeSO4. What is the concentration of nitrite in the bacon as parts per million?
Chromel is an alloy composed of nickel, iron and chromium.A 0.6472 g sample was dissolved and diluted to 250 mL. When a50 mL aliquot of 0.05182 M EDTA was mixed with an equal volumeof the diluted sample and all the three ions were chelated, a 5.11 mLback titration with 0.06241 M copper (II) was required.The chromium in a second 50 mL aliquot was masked through theaddition of hexamethylenetetramine, titration of the Fe and Nirequired 36.28 mL of 0.05182 M EDTA.Iron and chromium were masked with pyrophosphate in a third50 mL aliquot and the nickel was titrated with 25.91 mL of theEDTA solution.Calculate the percentage of nickel, chromium and iron in thealloy.
What is hardness of water? How can it be determined by using EDTA in a laboratory? Inan experiment to determine the hardness, a sample 100 ml of water required 15 ml of N/50EDTA. 100ml. of water after boiling for 15 minutes and making up to 100 ml again withdistilled water, required 8 ml of EDTA for titration. Calculate total, temporary and permanenthardness of water
A dried sample of commercial salt was prepared by a coning and quartering. A 0.911-g sample of the salt was dissolved and diluted to 250.0 mL in a volumetric flask. Repeat 10.00-mL aliquots of this solution were titrated with a 0.054 M silver nitrate solution, requiring 9.68 mL to reach equivalence. Calculate the %(w/w) NaCl in the original sample.
The DO of a water sample used in a steel industry was tested by Winkler’s method. The following titre values were obtained: Titration of 100 ml water added with MnSO4, alkaline KI solution and conc. H2SO4 in prescribed quantities with sodium thiosulphate solution gave three values, 8 ml, 8.2 ml, 8.2 ml. The titration of thio solution used for titration with 20 ml standard K2Cr2O7 (0.01 N) solution resulted in three values, 19.5 ml, 19.8 ml and 19.8 ml. Estimate the amount of DO present in the given water in ppm..
An EDTA solution was prepared by dissolving approximately 3 grams of Na2H2Y•H2O in sufficient water to give 1 liter of solution. This solution was then standardized against 50.00 mL aliquots of 0.004517 molar Mg2+. An average titration volume of 32.22 mL was required. Determine the molar concentration of EDTA.