4. You need to make a buffer with pH as close to 10.00 as possible. Two sets of weak acids and conjugate bases, with the Ka values, are listed below. Which of the two sets would be the best choice? You want a pKa close to the pH. Explain your reasoning. CH3COOH/CH3COO HCO3 /CO;? Ka = 1.80 x 105 Ka = 2.14 x 10-10

Chemistry & Chemical Reactivity
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ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
Section: Chapter Questions
Problem 15PS: A buffer is composed of formic acid and its conjugate base, the formate ion. (a) What is the pH of a...
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4. You need to make a buffer with pH as close to 10.00 as possible. Two sets of weak acids
and conjugate bases, with the Ka values, are listed below. Which of the two sets would
be the best choice? You want a pka close to the pH. Explain your reasoning.
CH:COOH/CH;coo HCO; /CO,2-
Ka = 1.80 x 10s
Ka = 2.14 x 10-10
%3D
%3D
5. 5 drops of a strong base (0.1 M concentration) was added to a buffer (pH = 7.0), with no
apparent change in pH. An additional 5 ml of this strong base was added, and the pH of
the solution increased to 13.0. Explain why there was no apparent change in pH in the
%3D
first case, but a marked change in pH in the second case.
Transcribed Image Text:4. You need to make a buffer with pH as close to 10.00 as possible. Two sets of weak acids and conjugate bases, with the Ka values, are listed below. Which of the two sets would be the best choice? You want a pka close to the pH. Explain your reasoning. CH:COOH/CH;coo HCO; /CO,2- Ka = 1.80 x 10s Ka = 2.14 x 10-10 %3D %3D 5. 5 drops of a strong base (0.1 M concentration) was added to a buffer (pH = 7.0), with no apparent change in pH. An additional 5 ml of this strong base was added, and the pH of the solution increased to 13.0. Explain why there was no apparent change in pH in the %3D first case, but a marked change in pH in the second case.
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