For the following reactions below:Give the major product of the reaction. Be specific with stereo- and regio-chemistry. Then for each reaction providethe mechanism, SN1, E1, SN2 or E2 that is a prevalent mechanistic step in the reaction (there is only one correctanswer per reaction)a.productSN1, E1, SN2or E2 - likemechanism?1. TSCI, pyridine2.CHproductSN1, E1, SN2or E2 - ikePOCI,mechanism?pyridine, 0°CproductSN1, E1, SN2or E2 - likemechanism?H,C H1. PCl, pyridine2. OCENн онproductSN1, E1, SN2or E2 - likemechanism?HH.SN1, E1, SN2or E2 - likemechanism?H.productOHHCIIACH

Answered: Image /qna-images/answer/2a19c483-a519-471d-99fb-08a86e519405.jpg

Answered: For the following reactions below: Give…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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When Br2 is added to buta-1,3-diene at -15 °C, the product mixture contains 60% ofproduct A and 40% of product B. When the same reaction takes place at 60 °C, theproduct ratio is 10% A and 90% B.(a) Propose structures for products A and B. (Hint: In many cases, an allylic carbocationis more stable than a bromonium ion.)
In the chemical reaction between 1-Bromobutane and ethanolic silver nitrate solution, a precipitate is barely formed. Using the skeletal structures of the molecules, write out the skeletal structure of each reaction (don't include the mechanism). Identify what the nucleophile is in each type of reaction, especially the SN1 reaction. Explain the reactivity of each electrophile/substrate in terms of whether they are tertiary, secondary, primary, etc. for each reaction. Include the overall chemical reaction.
When Br2 is added to buta-1,3-diene at -15 °C, the product mixture contains 60% ofproduct A and 40% of product B. When the same reaction takes place at 60 °C, theproduct ratio is 10% A and 90% B.(a) Propose structures for products A and B. (Hint: In many cases, an allylic carbocationis more stable than a bromonium ion.)(b) Propose a mechanism to account for formation of both A and B.(c) Show why A predominates at -15 °C and B predominates at 60 °C.(d) If you had a solution of pure A, and its temperature were raised to 60 °C, what wouldyou expect to happen? Propose a mechanism to support your prediction
In the chemical reaction between bromocyclopentane and ethanolic silver nitrate solution, a precipitate is definitely formed. Using the skeletal structures of the molecules, write out the skeletal structure of each reaction (don't include the mechanism). Identify what the nucleophile is in each type of reaction, especially within this SN1 reaction. Explain the reactivity of each electrophile/substrate in terms of whether they are tertiary, secondary, primary, etc. for each reaction. Include the overall chemical reaction.
In the chemical reaction between bromocyclohexane and ethanolic silver nitrate solution, a precipitate is definitely formed. Using the skeletal structures of the molecules, write out the skeletal structure of each reaction (don't include the mechanism). Identify what the nucleophile is in each type of reaction, especially within this SN1 reaction. Explain the reactivity of each electrophile/substrate in terms of whether they are tertiary, secondary, primary, etc. for each reaction. Include the overall chemical reaction.
1. Which of the following is the strongest nucleophile? Refer to the diagram below with an MeOH, MeSH, etc. 2. Which of the following is true about the stereochemistry of SN1 reaction?a.retention of configuration at the electrophilic centerb.50:50 mixture of retention and inversion of configuration at the electrophilic centerc.inversion of configuration at the electrophilic centerd. slightly more inversion than retention at the electrophilic center
After E2 elimination, will the following molecule contain deuterium? Why or why not?
A.) Draw two schemes, For the first scheme combine A and B. For the second, combine A and C. b.) For each scheme predict all products. c.) Label the major and minor products d.) Show all stereochemical configurations in the products, give reasons regarding sterochemical outcomes for each rxn. e.) Propose an appropriate solvent for each scheme, give a reason. f.) Discuss what by what mechanism your products are formed and why. (SN2, E2, E1, SN1)
When Br2 is added to buta-1,3-diene at -15 °C, the product mixture contains 60% ofproduct A and 40% of product B. When the same reaction takes place at 60 °C, theproduct ratio is 10% A and 90% B.Show why A predominates at -15 °C and B predominates at 60 °C.
Show an actual arrow-pushing mechanism for the transformation below, and briefly explain the observed regioselectivity.
In the chemical reaction between crotyl chloride and ethanolic silver nitrate solution, a precipitate is definitely formed. Using the skeletal structures of the molecules, write out the skeletal structure of each reaction (don't include the mechanism). Identify what the nucleophile is in each type of reaction, especially within this SN1 reaction. Explain the reactivity of each electrophile/substrate in terms of whether they are tertiary, secondary, primary, etc. for each reaction. Include the overall chemical reaction.
In the chemical reaction between 2-chloro-2-methyl-propane and ethanolic silver nitrate solution, a precipitate is definitely formed. Using the skeletal structures of the molecules, write out the skeletal structure of each reaction (don't include the mechanism). Identify what the nucleophile is in each type of reaction, especially within this SN1 reaction. Explain the reactivity of each electrophile/substrate in terms of whether they are tertiary, secondary, primary, etc. for each reaction. Include the overall chemical reaction.

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