8. Consider a molecule with a molecular formula of H,NCH;CH2CO2H. Complete the Lewisstructure showing all bonds and all lone pairs. Determine the hybridization of each atom.H H H OH N C C CH.H H.300

Following is the Lewis structure of the given organic molecule and the hybridisation.

Answered: 8. Consider a molecule with a molecular…

Chemistry

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Chapter9: Covalent Bonding: Orbitals

Section: Chapter Questions

Problem 82CWP: Pelargondin is the molecule responsible for the red color of the geranium flower. It also...

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Numerous molecules are detected in deep space. Three of them are illustrated here. (a) Are these compounds isomers? (b) Indicate the hybridization of each C atom in each molecule. (c) What is the value of the HCH angle in each of the three molecules? (d) Which of these molecules is/are polar? (e) Which molecule should have the strongest carbon-carbon bond? The strongest carbon-oxygen bond?
Which of the following molecules or ions are para-magnetic? What is the highest occupied molecular orbital (HOMO) in each one? Assume the molecular orbital diagram in Figure 9.16 applies to all of them. (a) NO (b) OF (c) O22 (d) Ne2+
What hybridization is required for central atoms that have a tetrahedral arrangement of electron pairs? A trigonal planar arrangement of electron pairs? A linear arrangement of e lectron pairs? How many unhybridized p atomic orbitals are present when a central atom exhibits tetrahedral geometry? Trigonal planar geometry? Linear geometry? What are the unhybridized p atomic orbitals used for? Describe the bonding in H2S, CH4, H2CO, and HCN, using the localized electron model.
Consider acetyl salicylic acid, better known as aspirin. Its structure is (a) How many sigma and pi bonds are there in aspirin? (b) What are the approximate values of the angles marked (in blue) A, B, and C? (c) What is the hybridization of each atom marked (in red) 1, 2, and 3?
Pelargondin is the molecule responsible for the red color of the geranium flower. It also contributes to the color of ripe strawberries and raspberries. The structure of pelargondin is: How many and bonds exist in pelargondin? What is the hybridization of the carbon atoms marked 14?
Minoxidil (C9H15N15O) is a compound produced by the Pharmacia Upjohn Company that has been approved as a treatment for some types of male pattern baldness. Note that in such shorthand ring structures, each point where lines meet is a carbon atom and that the hydrogen atoms bonded to the carbon atoms in the rings have been omitted. There will be four bonds to each carbon atom. a. Give the hybridization of the five nitrogen atoms in minoxidil. b. Give the hybridization of each of the nine carbon atoms in minoxidil. c. Give the approximate values for the bond angles marked a, b, c, d, e, and f. d. Including all the hydrogen atoms, how many bonds exist in minoxidil? e. How many bonds exist in minoxidil?
Allene (1,2-propadicne), a gas, has the following structure: What is the hybridization at each carbon atom? What is the geometry about each carbon atom? Using valencebond theory, describe the bonding about the center carbon atom. 1,3-dichloroallene is a derivative of allene with the following structure: Is this a polar molecule? (If you have difficulty visualizing the structure of this molecule, you might build a molecular model of it.)
The molecular orbital diagram of NO shown in Figure 10.47 also applies to the following species. Write the molecular orbital electron configuration of each, indicating the bond order and the number of unpaired electrons. (a) CN (b) CO (c) BeB (d) BC+ Figure 10.47 Molecular orbital diagram for nitric oxide (NO). The molecular orbital diagram for NO predicts a bond order of 2.5 and predicts that the molecule is paramagnetic with one unpaired electron. These predictions are verified by experimental measurements.
Why do we hybtidize atomic orbitals to explain the bonding in covalent compounds? What type of bonds form from hybrid orbitals: sigma or pi? Explain.
Specify the electron-pair and molecular geometry for each underlined atom in the following list. Describe the hybrid orbital set used by this atom in each molecule or ion. (a) CSe2 (b) SO2 (c) CH2O (d) NH4ss
Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) How many sigma bonds are in the molecule? (b) How many pi bonds are in the molecule? (c) What is the hybridization of the carbon atom bonded to nitrogen? (d) What is the hybridization of the carbon atom bonded to oxygen? (e) What is the hybridization of the double-bonded oxygen?

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8. Consider a molecule with a molecular formula of H,NCH;CH2CO2H. Complete the Lewis structure showing all bonds and all lone pairs. Determine the hybridization of each atom. H H H O H N C C C H. H H . 300