If AG' for the following reaction is -1.73 x 103 J, calculate E cell Cr20,2-(aq) + 2 Al(s) + 14 H*(aq) → 2 Cr³*(aq) + 2 Al3*(aq) + 7 H2O(e) a. +1.49 V b. +2.18 V с. +2.99 V d. +4.48 V e. +5.98 V
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- Zinc may be directly leached from zinc-lead sulphide concentrates by reaction with sulphuricPbS(s) + H2SO4 + 1 O2(g) → PbSO4(solid) + S° + H2O 21ZnS(s) + H2SO4 + 2 O2(g) → ZnSO4(aq) + S° + H2Oacid and oxygen. In addition, lead sulphide will be oxidized to give insoluble lead sulphate:Assume that a plant is to treat 400 t/day of concentrate containing 20.0 weight % Zn as ZnS and 110.0 weight % Pb and PbS. The concentrate and leach solution enters the leaching vessel at 32.0% solids. During the leach, 85.0% of the zinc is extracted and all the lead sulphide is oxidized. After the leaching step, the slurry passes to a thickener.(a) Calculate the concentration of Zn (in g/L) in the solution passing to metal recovery. Assume a solution density of 1.11 g/mL.(b) Calculate the tonnes per day of elemental sulphur produced.NOTE: “% solids†is the solids content of a slurry (consisting of particles and solution) and is defined as…If a dilute H2 SO4 solution is electrolyzed with copper electrodes, the most likely electrode reactions are 2H ^ + + 2e- = H2 (g) at the cathode and 2Cu (s) + H2O = Cu2O (s) + 2H ^ + + 2e- at the anode. If we observe the formation of 27.4 cm3 of moist hydrogen (751 barometric torrs, 23.3 ° C) at the cathode, what change in weight will there be simultaneously at the anode? Data: Pv H2O 23.3 ° C = 22 torr.Atomic mass: Cu (65); O (16); H (1)Gravimetric analysis of Fe3O4 (MW = 232 g/mole) may be undertaken with the following reactions: Fe3O4 → Fe2O3 → Fe (OH)3. Weight of sample containing 8.00% Fe3O4 that must be taken to obtain a precipitate of Fe(OH)3 (MW = 107 g/mole) that weighs 150 mg is . a. 0.108 g b. 0.325 g c. 1.355 g d. 4.065 g Amount of Fe2O3 (MW = 160 g/mole) from which 150 mg of Fe(OH)3 (MW = 107 g/mole) may be obtained is . a. 0.112 g b. 0.224 g c. 0.448 g d. none of the other choices
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- 2V is applied across an electrolytic cell containing 1.0M NaNO3. What reaction occurs at the anode? Show your work What reaction occurs at the cathode? Show your work Diagram the cell (assume the two electrodes are in 1 beaker). How many minutes does it take to form 10.0L of your anodic product measured at 99.8kPa and 28oC if a current of 1.3A is passed through the electrolytic cell?7. Consider a1Msolution ofNa3AsO4. Write the charge and mass balance equations for this system. (please type answer not write by hend)A student prepares a stock solution of BaF2 by dissolving 50.00g of a BaF2 in 1.00L of water. An additional 2 drops of 37% (w/v) HCl was added to acidify the solution. How many mL of the stock solution will be transferred to preparea 100.00 mL solution with 0.10 M BaF2 solution?
- Chemistry Calcium in a 5.00 mL urine sample was precipitated, redissolved and required 16.15 mL of 0.1157 N KMnO4. Calculate the % (w/v) of calcium in the urine.What is the concentration of ions in the soil solution after fertilizer application? Suppose that 122 pounds of K+ were applied per acre, then a gentle rain soaked the top 10 inches of soil to field capacity, which for the given soil was about 16% water by volume. If the K+ was applied as KCl, it is plausible that it all dissolved and distributed relatively uniformly with the infiltrating water. If so, then what was the K+ concentration in the soil solution in mol K+/L solution? Note that the volume can be computed like we do for an acre-furrow-slice (AFS), as area times depth. This is going to be a relatively small number, so please report your answer in mol K+/L solution to at least 5 decimal places.A solution containing 0.402 49 g of CoCl2 ? xH2O (a solid with an unknown number of waters of hydration) was exhaustively electrolyzed to deposit 0.099 37 g of metallic cobalt on a platinum cathode by the reaction Co21 1 2e2¡Co1s2. Calculate the number of moles of water per mole of cobalt in thereagent. A good approach is to find moles of Co, moles of CoCl2, mass of CoCl2, and, by difference, mass of H2O in the sample.
