Can you please answer these two sub questions and show the step by step to the solution please and thank you

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter15: Complex Acid/base Systems
Section: Chapter Questions
Problem 15.27QAP
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Can you please answer these two sub questions and show the step by step to the solution please and thank you 

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