2. Using the Tanabe-Sugano diagram for an octahedral d' complex, predict the UV- Vis spectra (make a plot of absorption vs. energy), list the term symbols of the spin- allowed transitions and the spin-forbidden transitions, and indicate the region of high absorption due to charge transfer for the following two cases: a) A/B = 10 plot spin-allowed transitions spin-forbidden transitions b) Ao/B = 30 plot spin-allowed transitions spin-forbidden transitions

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter24: Introduction To Spectrochemical Methods
Section: Chapter Questions
Problem 24.21QAP
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2. Using the Tanabe-Sugano diagram for an octahedral d' complex, predict the UV-
Vis spectra (make a plot of absorption vs. energy), list the term symbols of the spin-
allowed transitions and the spin-forbidden transitions, and indicate the region of
high absorption due to charge transfer for the following two cases:
a) A/B = 10
plot
spin-allowed transitions
spin-forbidden transitions
b) Ao/B = 30
plot
spin-allowed transitions
spin-forbidden transitions
Transcribed Image Text:2. Using the Tanabe-Sugano diagram for an octahedral d' complex, predict the UV- Vis spectra (make a plot of absorption vs. energy), list the term symbols of the spin- allowed transitions and the spin-forbidden transitions, and indicate the region of high absorption due to charge transfer for the following two cases: a) A/B = 10 plot spin-allowed transitions spin-forbidden transitions b) Ao/B = 30 plot spin-allowed transitions spin-forbidden transitions
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