Answered: ld states (to support your explanation…

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Chemistry

ld states (to support your explanation show the filling of the orbitals) b) Radiative transitions (to sup

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.1: Molecular Orbitals Of Conjugated Pi Systems

Problem 1P

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Question

By using the given 1) electronic absorption spectrum, 2) the Tanabo-Sugano diagram
for d3 complex in octahedral ligand field and 3) the absorption/emission spectra,
explain the following:

a) Ligand field states (to support your explanation show the filling of the orbitals)

b) Radiative transitions (to support your explanation refer to fluorescence,
phosphorescence and Stokes’ shift)

1) 10000
Mcm)
1000-
100
9
200
300
500
Ainm)
600
3)
elM-1cmly
2)
Energy --
i
2014
4110
700
100 4F
Free lon Increasing Field
Flcm x 103)
Absorption (-,298 K) and emission (-, 77 K) spectra
ATig
2012
12324
210
लूलै রধ
-2E4
2020120

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