According to Zaitsev's Rule, dehydration of 2-methyl-2-heptanol (using H2SO4 and heat) produces 2-methyl-2-heptene as the major substrate product. True False
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- Starting with 2-methylpropene, outline a synthesis of (a) (CH3)3COH (b) (CH3)2C(OH)CH2BrShow how to convert propene to this compound , using any inorganic reagents as necessary. Q.) 1-ChloropropaneIn each case below select the synthetic procedure/s that could be used to carry out the transformation, giving the alcohol shown as the single major product.The procedures are:Hydroboration/oxidation: alkene + BH3; then H2O2, -OH.Oxymercuration: alkene + Hg(OAc)2, H2O; then NaBH4
- α-Terpinene, C10H16, is a pleasant-smelling hydrocarbon that has been isolated from oil of marjoram. On hydrogenation over a palladium catalyst, α-terpinene reacts with 2 molar equivalents of H2 to yield a hydrocarbon, C10H20. On ozonolysis, followed by reduction with zinc and acetic acid, α-terpinene yields two products, glyoxal and 6-methyl-2,5- heptanedione. (a) How many degrees of unsaturation does a-terpinene have? (b) How many double bonds and how many rings does it have? (c) Propose a structure for a-terpinene.Alkenes can be hydrated to form alcohols by (1) hydroboration followed by oxidation with alkaline hydrogen peroxide and (2) acid-catalyzed hydration. Compare the product formed from each alkene by sequence (1) with those formed from (2). Q.)trans-2-ButeneStarting with acetylene and 1-bromobutane as the only sources of carbon atoms, show how to synthesize the following. Q.) Decane
- Name the major product of the reaction between (S)-2-bromohexane and KCH3COO. Be specific with the configuration.Alkenes can be hydrated to form alcohols by (1) hydroboration followed by oxidation with alkaline hydrogen peroxide and (2) acid-catalyzed hydration. Compare the product formed from each alkene by sequence (1) with those formed from (2). Q.) PropeneWhat is the exo product of (E)-2-methylhexa-1,3-diene plus nitroethene
- Showusing expanded form the complete halogenation (using Br and UV light) of 2-butyne (2equations). Name your products after the first and second reaction.Predict the products of dehydrohalogenation and dehydration reactions, and use Zaitsev’s rule to predict the major and minor productsThe academic version of the process invention program (PIP) contains several examples, as follows: HDAl-hydrodealkylation of toluene to produce benzene CYHEXl-cyclohexane production by hydrogenation of benzene STYRl-styrene production from ethylbenzene XYLl-production of m-xylene from toluene ANHYDl-reaction of acetone and acetic acid to form acetic anhydride BUTALl-alkylation reaction of butene-1 and isobutane to produce iso-octane Select the “new plant design” mode and the “look at existing flow sheet” option, and follow the synthesis steps for one of these processes. ‘Obtain the current flow sheet as output at each level of the synthesis procedure. Also list the heuristics used at each step.