CI F C-CI F-F + CI- -Cㅡ-CI -C-F F-F CI-CI ČI +

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter5: Resonance
Section: Chapter Questions
Problem 1CTQ: Which elements on the periodic table (other than H) are likely to form a+1 cation?
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Use the molar bond enthalpy data in the table to estimate the value of Δ?∘rxnΔ⁢Hrxn∘ for the equation

 

CCl4(g)+2F2(g)⟶CF4(g)+2Cl2(g)CCl4⁢(g)+2⁢F2⁡(g)⟶CF4⁢(g)+2⁢Cl2⁢(g)

 

The bonding in the molecules is shown.

Average molar bond enthalpies (?bond)(Hbond)

Bond ??⋅???−1kJ⋅mol−1 Bond ??⋅???−1kJ⋅mol−1
O−HO−H 464464 C≡NC≡N 890890
O−OO−O 142142 N−HN−H 390390
C−OC−O 351351 N−NN−N 159159
O=OO=O 502502 N=NN=N 418418
C=OC=O 730730 N≡NN≡N 945945
C−CC−C 347347 F−FF−F 155155
C=CC=C 615615 Cl−ClCl−Cl 243243
C≡CC≡C 811811 Br−BrBr−Br 192192
C−HC−H 414414 H−HH−H 435435
C−FC−F 439439 H−FH−F 565565
C−ClC−Cl 331331 H−ClH−Cl 431431
C−BrC−Br 276276 H−BrH−Br 368368
C−NC−N 293293 H−SH−S 364364
C=NC=N 615615 S−SS−S 225

 

CI
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Transcribed Image Text:CI F F-F CI-CI -C-CI + F-Č-F + CI- F-F C-CI
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