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- A 1, 2-cis disubstituted cyclohexane, such as cis-1, 2-dichlorocyclohexane, must have one group axial and one group equatorial. Explain.Complete this graph of relative potential energy vs. rotation of the C1C2 bond of ethane. Thepoint drawn for you indicates the P.E. at 0° (eclipsed).(a)(2R,3S)-2,3-dibromohexane, draw a three-dimensional representation.
- Rank the following groups in order of decreasing priority. −H, −CH3, −Cl, −CH2ClShow the delocalization of charge in the following structure, draw the resonance forms and indicate the movement of electrons with a curved arrow CH2=CH-OTrue or False: 1. The eclipsed conformation of a linear alkane IS called cis, while the anti conformation of an alkane IS called trans. 2. In the conversion of open-chain D-glucose to the ring form, the aldehyde carbon (carbon #1) bonds to the oxygen on carbon number 5 to form a ring that is both PYRANOSE and UNLOCKED.
- Propose structures for hydrocarbon molecules that meet the following descriptions: (2 pts.each)(a) Contains 4 sp2-hybridized carbons and 2 sp-hybridized carbons (b) Contains only 5 carbons, all of which are sp3-hybridized (c) Contains 2 sp3-hybridized carbons and 4 sp-hybridized carbonsGiven the following partial structure, add a substituent X to C-1 so that it satisfies the indicated stereochemical requirement. What is the A -C - C - X torsion (dihedral) angle in each?Rings + Unsaturation --- Hydrogenation If compound A C51H81BrN5O3P3 is hydrogenated to give compound B C51H101BrN5O3P3. How many rings does compound A have? Assume that P has a valency of 5. Would the answer be 4 rings? Formula -> unsat + rings = 1+C +N/2 - H/2 - X/2
- onsider the methyl group at the junction of rings A and B. Is it axial or equatorial to ring A? Is it axial or equatorial to ring B?draw double-newman projection for 1. neopentane, 2. isobutyl bromide, 3. sec-butylcyclopentane, 4. trans-1,2-dichlorocyclopropane.A.) On any clean sheet of paper, draw both the condensed and line-bond structure of the following compounds: 4) bromocyclobutane (Br-, Bromo branch) 5) 5-sec-butylnonane 6) 4-t-butylheptane 7) 4-ethylcycloheptene 8) 4,4-dimethylpent-2-ene 9) 3-chloro-2,7-dimethylnon-4-yne (Cl- Chloro branch) 10) 1-cyclohexylbut-2-yne