CO₂E1 CH3CHCO₂E1 1. Na+ "QEt 2. PhBr 3. H30¹, heat prevented. CH3 I CHCO₂H The intended reaction is the involves alkylation of the enolate ion. However, the reaction will not occur because the alkyl halide used is since the is which
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- There are two isomeric cyclohexa-1,4-diene products when benzoic acid undergoes the Birch reduction (see Problem 25.24). (a) Draw the mechanism that leads tothe formation of the major product. (b) Will the Birchreduction of benzoic acid occur faster or slower than theBirch reduction of benzene itself? Hint: Is –CO2H anelectron-donating or an electron-withdrawing group?Which halide in the attached marine natural product reacts fastest inthe SN2 reaction?The following product was obtained from the ozonolysis of alkene what is the structure of the alkene???
- 1. what is the Nature of the leaving group (LG)? 2. what is the relative size of activation energy (Ea) for each reaction? 3. what is the Hammond's postulate? 4. what are the Relative thermodynamic stability of the reactive intermediates? 5. what is Influence of the solvent (if given) on the reactions and intermediates?Chemistry please provide the flow of electrons aswell!! thank you! using the starting material (on the left) to determine the sythetic route which will be the most reaosnable and effective to theres none, you have to start witth the begin products to get to finish needed by using the minmium reagents and reactions needed to get to the final product1.Draw the product, please shows step by step in details 2.Explain if (CH3)2CH in this reaction can attach in ortho positon in Friedel Craft Alkylation?? why or why not???
- In SN2 reactions of haloalkanes, the order of reactivity is RI>RBr>RCl>RF. Alkyl iodides are considerably more reactive than alkyl fluorides, often by factors as great as 106. All 1-halo-2,4-dinitrobenzenes, however, react at approximately the same rate in nucleophilic aromatic substitutions. Account for this difference in relative reactivities.An inexperienced graduate student treated dec-5-ene with borane in THF, placed the flask in a refrigerator, and left for aparty. When he returned from the party, he discovered that the refrigerator was broken and that it had gotten quite warminside. Although all the THF had evaporated from the flask, he treated the residue with basic hydrogen peroxide. Tohis surprise, he recovered a fair yield of decan-1-ol. Use a mechanism to show how this reaction might have occurred.(Hint: The addition of BH3 is reversible.)Which of A to E shows the product that will be obtained from the reaction of (Z)-hex-2-ene with MeCO3H?
- There are two isomeric cyclohexa-1,4-diene products when toluene undergoes the Birch reduction (see Problem 25.24). (a) Draw the mechanism that leads to the formation of the major product. (b) Will the Birchreduction of toluene occur faster or slower than the Birch reduction of benzene itself? Hint: Is –CH3 an electron-donating or an electron-withdrawing group?Attached compounds undergoes E2 elimination with strongbase? For compounds that undergo elimination, draw the product. Forcompounds that do not undergo elimination, explain why they are unreactive.Show the SN2 mechanism in the reaction between (S) 2-bromobutane and iodide ion. Label the product and draw a enery diagram for this reaction.