Consider a battery made from one half-cell that consists of a copper electrode in 1 M CuSO4 solution and another half-cell that consists of a lead electrode in 1 M Pb(NO3)2 solution.(a) What are the reactions at the anode, cathode, and the overall reaction?(b) What is the standard cell potential for the battery?(c) Most devices designed to use dry-cell batteries can operate between 1.0 and 1.5 V. Could this cell be used to make a battery that could replace a dry-cell battery? Why or why not.(d) Suppose sulfuric acid is added to the half-cell with the lead electrode and some PbSO4(s) forms. Would the cell potential increase, decrease, or remain the same?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.49QE: A half-cell that consists of a copper wire in a 1.00 M Cu(NO3)2 solution is connected by a salt...
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Consider a battery made from one half-cell that consists of a copper electrode in 1 M CuSO4 solution and another half-cell that consists of a lead electrode in 1 M Pb(NO3)2 solution.
(a) What are the reactions at the anode, cathode, and the overall reaction?
(b) What is the standard cell potential for the battery?
(c) Most devices designed to use dry-cell batteries can operate between 1.0 and 1.5 V. Could this cell be used to make a battery that could replace a dry-cell battery? Why or why not.
(d) Suppose sulfuric acid is added to the half-cell with the lead electrode and some PbSO4(s) forms. Would the cell potential increase, decrease, or remain the same?

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