Consider a hypothetical diprotic acid (H2A) with pKa1 = 7.301 and pKa2 = 10.00. A 40.0-mL sample of a 0.050 0 M solution of the disodium salt of this acid (Na2A) is titrated with 0.100 M HCl. a) Calculate the pH at 5.00-mL intervals of titrant added from 0 to 50 mL. b) Sketch the titration curve. c) What would be an ideal pKa for an indicator to use in this titration?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter15: Acid-base Equilibria
Section: Chapter Questions
Problem 88AE: Consider die titration of 50.0 mL of 0.10 M H3A (Ka1 = 5.0 104, Ka2 = 1.0 108, Ka3 = 1.0 1012)...
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 Consider a hypothetical diprotic acid (H2A) with pKa1 = 7.301 and pKa2 = 10.00. A
40.0-mL sample of a 0.050 0 M solution of the disodium salt of this acid (Na2A) is
titrated with 0.100 M HCl.
a) Calculate the pH at 5.00-mL intervals of titrant added from 0 to 50 mL.
b) Sketch the titration curve.
c) What would be an ideal pKa for an indicator to use in this titration?

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