Consider a molecule that that has three conformations labelled A, B and C. Conformations A and B are non-degenerate, while conformation C has a degeneracy of three. The energies relative to conformation A (which is the most stable) are found to be +5.75 kJ/mol for conformation B, and +7.32 kJ/mol for conformer C. At 300 K, what are the populations of each conformer in percent. Show your work.

Physical Chemistry
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ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter18: More Statistical Thermodynamics
Section: Chapter Questions
Problem 18.4E
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Consider a molecule that that has three conformations labelled A, B and
C. Conformations A and B are non-degenerate, while conformation C has a
degeneracy of three.
The energies relative to conformation A (which is the most stable) are found to be
+5.75 kJ/mol for conformation B, and +7.32 kJ/mol for conformer C.
At 300 K, what are the populations of each conformer in percent.
Show your work.
Transcribed Image Text:Consider a molecule that that has three conformations labelled A, B and C. Conformations A and B are non-degenerate, while conformation C has a degeneracy of three. The energies relative to conformation A (which is the most stable) are found to be +5.75 kJ/mol for conformation B, and +7.32 kJ/mol for conformer C. At 300 K, what are the populations of each conformer in percent. Show your work.
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