Consider BF3 (point group D3h). There are SALCs from the F valence orbitals which transform as A″2 and E″. Are there any valence orbitals of the central B atom that can have a non-zero overlap with these SALCs? How would your conclusion differ for AlF3, where 3d orbitals might be available?
Consider BF3 (point group D3h). There are SALCs from the F valence orbitals which transform as A″2 and E″. Are there any valence orbitals of the central B atom that can have a non-zero overlap with these SALCs? How would your conclusion differ for AlF3, where 3d orbitals might be available?
Modern Physics
3rd Edition
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Chapter7: Tunneling Phenomena
Section: Chapter Questions
Problem 18P
Related questions
Question
Consider BF3 (point group D3h). There are SALCs from the F valence orbitals which transform as A″2 and E″. Are there any valence orbitals of the central B atom that can have a non-zero overlap with these SALCs? How would your conclusion differ for AlF3, where 3d orbitals might be available?
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.Recommended textbooks for you
Modern Physics
Physics
ISBN:
9781111794378
Author:
Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:
Cengage Learning
Modern Physics
Physics
ISBN:
9781111794378
Author:
Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:
Cengage Learning