Consider (S)-2-chlorobutane reacting with methanol, CH3OH a) Write a balanced equation, clearly indicate stereochemistry of the reactants) and the product(s). b) Show the mechanism of this reaction. Be sure to show all relevant lone pairs of electrons, charges, intermediates, transition states, and "electron-pushing" arrows. c) Draw and label a reaction energy diagram for this reaction. Assume the reaction is exothermic overall. d) Predict the rate law for this reaction. e) Which will react faster with HOCH3, (SL 2 chlorobutane or 2 bromo 2.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter15: Radical Reactions
Section: Chapter Questions
Problem 12E
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Consider (S)-2-chlorobutane reacting with
methanol, CH3OH
a) Write a balanced equation, clearly
indicate stereochemistry of the reactants)
and the product(s).
b) Show the mechanism of this reaction. Be
sure to show all relevant lone pairs of
electrons, charges, intermediates, transition
states, and "electron-pushing" arrows.
c) Draw and label a reaction energy
diagram for this reaction. Assume the
reaction is exothermic overall.
d) Predict the rate law for this reaction.
e) Which will react faster with HOCH3,
(S)-2-chlorobutane or 2-bromo-2-
methylbutane? Why?
Transcribed Image Text:Consider (S)-2-chlorobutane reacting with methanol, CH3OH a) Write a balanced equation, clearly indicate stereochemistry of the reactants) and the product(s). b) Show the mechanism of this reaction. Be sure to show all relevant lone pairs of electrons, charges, intermediates, transition states, and "electron-pushing" arrows. c) Draw and label a reaction energy diagram for this reaction. Assume the reaction is exothermic overall. d) Predict the rate law for this reaction. e) Which will react faster with HOCH3, (S)-2-chlorobutane or 2-bromo-2- methylbutane? Why?
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