Consider the C2v molecule OF2; take the molecule to lie in the yz-plane, with z directed along the C2 axis; the mirror plane σ′v is the yz-plane, and σv is the xz-plane. The combination pz(A) + pz(B) of the two F atoms spans A1, and the combination pz(A) − pz(B) of the two F atoms spans B2. Are there any valence orbitals of the central O atom that can have a non-zero overlap with these combinations of F orbitals? How would the situation be different in SF2, where 3d orbitals might be available?
Consider the C2v molecule OF2; take the molecule to lie in the yz-plane, with z directed along the C2 axis; the mirror plane σ′v is the yz-plane, and σv is the xz-plane. The combination pz(A) + pz(B) of the two F atoms spans A1, and the combination pz(A) − pz(B) of the two F atoms spans B2. Are there any valence orbitals of the central O atom that can have a non-zero overlap with these combinations of F orbitals? How would the situation be different in SF2, where 3d orbitals might be available?
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter7: Molecular Structures
Section: Chapter Questions
Problem 65QRT
Related questions
Question
Consider the C2v molecule OF2; take the molecule to lie in the yz-plane, with z directed along the C2 axis; the mirror plane σ′v is the yz-plane, and σv is the xz-plane. The combination pz(A) + pz(B) of the two F atoms spans A1, and the combination pz(A) − pz(B) of the two F atoms spans B2. Are there any valence orbitals of the central O atom that can have a non-zero overlap with these combinations of F orbitals? How would the situation be different in SF2, where 3d orbitals might be available?
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 2 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Physical Chemistry
Chemistry
ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Physical Chemistry
Chemistry
ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,