Consider the corrosion of Fe in aqueous solutions under standard conditions. According to the standard EMF series, the standard reduction potential (V) for Fe(II) is −0.440 ?. What will happen to the reduction potential for Fe(II) when its concentration is much lower than 1 M. Why?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.108QE: At 298 K, the solubility product constant for solid Ba(IO3)2 is 1.5 109. Use the standard reduction...
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Consider the corrosion of Fe in aqueous solutions under standard conditions. According to the standard EMF series, the standard reduction potential (V) for Fe(II) is −0.440 ?. What will happen to the reduction potential for Fe(II) when its concentration is much lower than 1 M. Why? 

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