Consider the following complex mechansim: A + B → C + D with rate constant k1 C + D → A + B with rate constant k-1 C → B with rate constant k2 D → A with rate constant k3 A → D  with rate constant k-3 Write down expressions for d[A]/dt, d[B]/dt, d[C]/dt, and d[D]/dt

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter13: Kinetic Methods
Section: Chapter Questions
Problem 8P
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Consider the following complex mechansim:

A + B → C + D with rate constant k1

C + D → A + B with rate constant k-1

C → B with rate constant k2

D → A with rate constant k3

A → D  with rate constant k-3

Write down expressions for d[A]/dt, d[B]/dt, d[C]/dt, and d[D]/dt

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