Consider the following equilibrium: 2NOClg    +2NOgCl2g =       ΔG041.kJ Now suppose a reaction vessel is filled with  9.13atm  of nitrosyl chloride  NOCl  and  3.32atm  of nitrogen monoxide  NO  at  934.°C . Answer the following questions about this system: Under these conditions, will the pressure of  NO  tend to rise or fall?   rise     fall   Is it possible to reverse this tendency by adding  Cl2 ? In other words, if you said the pressure of  NO  will tend to rise, can that be changed to a tendency to fall by adding  Cl2 ? Similarly, if you said the pressure of  NO  will tend to fall, can that be changed to a tendency to rise by adding  Cl2 ?   yes     no   If you said the tendency can be reversed in the second question, calculate the minimum pressure of  Cl2  needed to reverse it. Round your answer to  2  significant digits.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter12: Gaseous Chemical Equilibrium
Section: Chapter Questions
Problem 56QAP: Sulfur oxychloride, SO2Cl2, decomposes to sulfur dioxide and chlorine gases. SO2Cl2(g)SO2(g)+Cl2(g)...
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Consider the following equilibrium:

2NOClg
  
+2NOgCl2g
=       ΔG041.kJ

Now suppose a reaction vessel is filled with 

9.13atm

 of nitrosyl chloride 

NOCl

 and 

3.32atm

 of nitrogen monoxide 

NO

 at 

934.°C

. Answer the following questions about this system:

Under these conditions, will the pressure of 
NO
 tend to rise or fall?
 
rise
 
 
fall
 
Is it possible to reverse this tendency by adding 
Cl2
?
In other words, if you said the pressure of 
NO
 will tend to rise, can that be changed to a tendency to fall by adding 
Cl2
? Similarly, if you said the pressure of 
NO
 will tend to fall, can that be changed to a tendency to rise by adding 
Cl2
?
 
yes
 
 
no
 
If you said the tendency can be reversed in the second question, calculate the minimum pressure of 
Cl2
 needed to reverse it.
Round your answer to 
2
 significant digits.
atm
 
 
 
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