Consider the following mechanism: A + e kf B C B C+eD E- = -0.2 V vs SHE EO 0.6 V vs SHE Now answer the following questions: (a) What would you expect voltammetry of a solution of C to yield? Sketch CVs at various sweep rates, labeling the fastest and slowest scans. (b) What would you expect voltammetry of a solution of A to yield? Sketch CVs at various sweep rates, labeling the fastest and slowest scans.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter25: Voltammetry
Section: Chapter Questions
Problem 25.1QAP
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Consider the following mechanism:
A + e
kf
B
C
B
C+eD
E-
= -0.2 V vs SHE
EO 0.6 V vs SHE
Now answer the following questions:
(a) What would you expect voltammetry of a solution of C to yield? Sketch CVs at various sweep
rates, labeling the fastest and slowest scans.
(b) What would you expect voltammetry of a solution of A to yield? Sketch CVs at various sweep
rates, labeling the fastest and slowest scans.
Transcribed Image Text:Consider the following mechanism: A + e kf B C B C+eD E- = -0.2 V vs SHE EO 0.6 V vs SHE Now answer the following questions: (a) What would you expect voltammetry of a solution of C to yield? Sketch CVs at various sweep rates, labeling the fastest and slowest scans. (b) What would you expect voltammetry of a solution of A to yield? Sketch CVs at various sweep rates, labeling the fastest and slowest scans.
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