Consider the insoluble compound silver iodide, AgI. The silver ion also forms a complex with cyanide ions. Write a balanced net ionic equation to show why the solubility of AgI(s) increases in the presence of cyanide ions and calculate the equilibrium constant for this reaction. For Ag (CN)₂ (aq), Kf = 1.3x102¹. Be sure to specify states such as (aq) or (s). Knet =

Consider the insoluble compound silver iodide, AgI. The silver ion also forms a complex with cyanide ions. Write a balanced net ionic equation to show why the solubility of AgI(s) increases in the presence of cyanide ions and calculate the equilibrium constant for this reaction. For Ag (CN)₂ (aq), Kf = 1.3x102¹. Be sure to specify states such as (aq) or (s). Knet =

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter12: Chemical Equilibrium

Section12.3: Determining Equilibrium Constants

Problem 12.3PSP

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Consider the insoluble compound cobalt(II) carbonate , CoCO3 . The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Co(NH3)62+ , Kf = 7.7×104 . Be sure to specify states such as (aq) or (s). + + K =
Consider the insoluble compound cobalt(II) hydroxide , Co(OH)2 . The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of Co(OH)2 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Co(NH3)62+ , Kf = 7.7×104 . Be sure to specify states such as (aq) or (s). + + K =
Consider the insoluble compound silver iodide , AgI . The silver ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of AgI (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Ag(NH3)2+ , Kf = 1.6×107 . Be sure to specify states such as (aq) or (s). + + K =
Consider the insoluble compound silver chloride , AgCl . The silver ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of AgCl (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Ag(NH3)2+ , Kf = 1.6×107 . Be sure to specify states such as (aq) or (s). + + K =
The reaction 2A(g) ⇌ B(g) is found to have Kp = 24.5. What would the equilibrium constant be for 2B(g) ⇌ 4A(g)?
Consider the insoluble compound cobalt(II) carbonate , CoCO3 . The cobalt(II) ion also forms a complex with ammonia . Write a balanced net ionic equation to show why the solubility of CoCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction.For Co(NH3)62+ , Kf = 7.7×104 . Be sure to specify states such as (aq) or (s).
We began the chapter with an informal discussion of how the mineral fluorite (as shown) is formed. Fluorite, CaF2, is a slightly soluble solid that dissolves according to the equation: CaF2(s) ⇌ Ca2+(aq) + 2F−(aq)The concentration of Ca2+ in a saturated solution of CaF2 is 2.15 × 10–4 M; therefore, that of F– is 4.30 × 10–4 M, that is, twice the concentration of Ca2+. What is the solubility product of fluorite?
The formation constant of a complex ion [M(NH3)4]2+(aq) is 1.8E8. If a solution is prepared by adding 0.3 mol of [M(NH3)4]Cl2 to 850.0 mL of water, what is the equilibrium concentration of free M2+(aq) ions?
For the chemical reaction that occurs when the precipitate forms, write a balanced, net-ionic equation for the reaction, and explain why the reaction is best represented by a net-ionic equation. Explain the purpose of drying and weighing the filter paper with the precipitate three times. In the filtrate solution, is [K+] greater than, less than, or equal to [NO3−] ? Justify your answer. Calculate the number of moles of precipitate that is produced in the experiment. Calculate the mass percent of I− in the tablet. In another trial, the student dissolves a tablet in 55.0 mL of water instead of 50.0 mL of water. Predict whether the experimentally determined mass percent of I− will be greater than, less than, or equal to the amount calculated in part (e). Justify your answer. A student in another lab also wants to determine the I− content of a KI tablet but does not have access to Pb(NO3)2 . However, the student does have access to 0.20 M AgNO3 , which reacts with I−(aq)…
Calculate the Molar Solubility at 25.0 oC of an aqueous solution of calcium phosphate, Ca3(PO4)2, given that its Ksp = 1.20 x 10–26 at 25.0 oC.
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