Consider the melting points of the substances below (see figures for some compounds). Explain the trend in melting point using your knowledge of intermolecular forces. Substance Melting Point (°C) Cl2 -102 isopentyl acetate (C7H14O2) -78 heptanoic acid (C7H14O2) -7.5 lycopene (C40H56) 69

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter9: Liquids, Solids, And Materials
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Consider the melting points of the substances below (see figures for some compounds). Explain the trend in melting point using your knowledge of intermolecular forces.

Substance

Melting Point (°C)

Cl2

-102

isopentyl acetate (C7H14O2)

-78

heptanoic acid (C7H14O2)

-7.5

lycopene (C40H56)

69

Expert Solution
Step 1

The stronger forces between the molecules is, the more the energy is required, to break them apart(in form of heat). Since they will need more heat, so they will have higher melting point. Hence, the intermolecular forces between the molecules impacts its melting point. There are three main types of intermolecular forces:

1. London dispersion forces 

2. Dipole-Dipole interactions

3. Hydrogen bonding

 

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