Consider the potential energy vs reaction coordinate diagram in problem 70 in your text on pg 616. Which of the answers below best describes the change in enthalpy for this reaction? Group of answer choices A) thermoneutral B) endothermic C) exothermic D) endogonic

Principles of Instrumental Analysis
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Chapter25: Voltammetry
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Consider the potential energy vs reaction coordinate diagram in problem 70 in your text on pg 616. Which of the answers below best describes the change in enthalpy for this reaction?

Group of answer choices
A) thermoneutral
B) endothermic
C) exothermic
D) endogonic
A Chemistry The Central Science by Theodore L. Brown H. Eugene LeMay Jr Bruce E. Bursten Catherine J. Murphy Patrick Woodward Matthew E. Stoltzfus (z-lib.org).pdf - Adobe Acrobat Pro DC (32-bit)
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14.74 You have studied the gas-phase oxidation of HBr by O2:
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4 HBr(g) + O2(8) → 2 H20(8) + 2 Br2(8)
You find the reaction to be first order with respect to HBr
and first order with respect to O2. You propose the follow-
ing mechanism:
Create PDF
Reaction progress
4i Combine Files
HBr(g) + O2(8)
HOOB1(g)
14.70 Consider the following energy profile.
HOOBI(g) + HBr(8)
2 HOBI(g)
HOBI(g) + HBr(8) → H20(g) + Br2(g)
Edit PDF
(a) Confirm that the elementary reactions add to give the
overall reaction. (b) Based on the experimentally deter-
mined rate law, which step is rate determining? (c) What
are the intermediates in this mechanism? (d) If you are
unable to detect HOBR or HOOBR among the products,
does this disprove your mechanism?
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A Request Signatur.
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Reaction progess
Catalysis (Section 14.7)
LO Export PDF
14.75 (a) What is a catalyst? (b) What is the difference between
E0 Organize Pages
(a) How many elementary reactions are
mechanism? (b) How many intermediates are formed in
the reaction? (c) Which step is rate limiting? (d) For the
overall reaction, is AE positive, negative, or zero?
the reaction
a homogeneous and a heterogeneous catalyst? (c) Do cat-
alysts affect the overall enthalpy change for a reaction,
the activation energy, or both?
Là Send for Comme.
14.71 The following mechanism has been proposed for the gas-
14.76 (a) Most commercial heterogeneous catalysts are ex-
tremely finely divided solid materials. Why is particle size
important? (b) What role does adsorption play in the ac-
tion of a heterogeneous catalyst?
phase reaction of H, with ICI:
Comment
H2(8) + ICI(8)
· HI(g) + HCI(g)
HI(8) + ICI(8) → L(8) + HCl(8)
14.77 In Figure 14.21, we saw that Br (ag) catalyzes the decom-
position of H,O2(aq) into H20(1) and O2(8). Suppose that
some KBr(s) is added to an aqueous solution of hydrogen
Edit PDF content
(a) Write the balanced equation for the overall reaction.
(b) Identify any intermediates in the mechanism. (c) If
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right in your PDF.
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4:05 PM
P Type here to search
61°F Mostly sunny
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2/19/2022
Potential energy
Transcribed Image Text:A Chemistry The Central Science by Theodore L. Brown H. Eugene LeMay Jr Bruce E. Bursten Catherine J. Murphy Patrick Woodward Matthew E. Stoltzfus (z-lib.org).pdf - Adobe Acrobat Pro DC (32-bit) File Edit View E-Sign Window Help Home Tools Chemistry The Cen. x Subscribe 656 / 1249 110% B A 14.74 You have studied the gas-phase oxidation of HBr by O2: Search tools 4 HBr(g) + O2(8) → 2 H20(8) + 2 Br2(8) You find the reaction to be first order with respect to HBr and first order with respect to O2. You propose the follow- ing mechanism: Create PDF Reaction progress 4i Combine Files HBr(g) + O2(8) HOOB1(g) 14.70 Consider the following energy profile. HOOBI(g) + HBr(8) 2 HOBI(g) HOBI(g) + HBr(8) → H20(g) + Br2(g) Edit PDF (a) Confirm that the elementary reactions add to give the overall reaction. (b) Based on the experimentally deter- mined rate law, which step is rate determining? (c) What are the intermediates in this mechanism? (d) If you are unable to detect HOBR or HOOBR among the products, does this disprove your mechanism? FEATURED A Request Signatur. Fill & Sign Reaction progess Catalysis (Section 14.7) LO Export PDF 14.75 (a) What is a catalyst? (b) What is the difference between E0 Organize Pages (a) How many elementary reactions are mechanism? (b) How many intermediates are formed in the reaction? (c) Which step is rate limiting? (d) For the overall reaction, is AE positive, negative, or zero? the reaction a homogeneous and a heterogeneous catalyst? (c) Do cat- alysts affect the overall enthalpy change for a reaction, the activation energy, or both? Là Send for Comme. 14.71 The following mechanism has been proposed for the gas- 14.76 (a) Most commercial heterogeneous catalysts are ex- tremely finely divided solid materials. Why is particle size important? (b) What role does adsorption play in the ac- tion of a heterogeneous catalyst? phase reaction of H, with ICI: Comment H2(8) + ICI(8) · HI(g) + HCI(g) HI(8) + ICI(8) → L(8) + HCl(8) 14.77 In Figure 14.21, we saw that Br (ag) catalyzes the decom- position of H,O2(aq) into H20(1) and O2(8). Suppose that some KBr(s) is added to an aqueous solution of hydrogen Edit PDF content (a) Write the balanced equation for the overall reaction. (b) Identify any intermediates in the mechanism. (c) If Make changes to text and images right in your PDF. Edit a PDF 4:05 PM P Type here to search 61°F Mostly sunny 4) 2/19/2022 Potential energy
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